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Solution
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Q.44 Correct
Q.44 In-correct
Q.44 Unattempt

Column - I lists the waves of the electromagnetic spectrum. Column - II gives approximate frequency range of these waves. Match Column - I and Column - II and choose the correct match from the given choices.

Column I Column II
(A) Radiowaves (P) $$
10^{18} \text { to } 10^{20} \mathrm{~Hz}
$$
(B) Microwaves (P) $$
10^{11} \text { to } 5 \times 10^{14} \mathrm{~Hz}
$$
(C) Infrared (R) $$
10^4 \text { to } 10^8 \mathrm{~Hz}
$$
(D) X-rays (S) $$
10^9 \text { to } 10^{12} \mathrm{~Hz}
$$

Column - I lists the waves of the electromagnetic spectrum. Column - II gives approximate frequency range of these waves. Match Column - I and Column - II and choose the correct match from the given choices.

Column I Column II
(A) Radiowaves (P) $$
10^{18} \text { to } 10^{20} \mathrm{~Hz}
$$
(B) Microwaves (P) $$
10^{11} \text { to } 5 \times 10^{14} \mathrm{~Hz}
$$
(C) Infrared (R) $$
10^4 \text { to } 10^8 \mathrm{~Hz}
$$
(D) X-rays (S) $$
10^9 \text { to } 10^{12} \mathrm{~Hz}
$$

Q.60 Correct
Q.60 In-correct
Q.60 Unattempt

The following are the graphs of potential barrier versus width of the depletion region for a p-n junction diode.

COMEDK 2024 Evening Shift Physics - Semiconductor Devices and Logic Gates Question 1 English

Which of the following is correct?

I II III IV`
A - unbiased diode A - Forward biased diode A - unbiased diode A - unbiased diode
B - Reverse biased B - Reverse biased B - Forward biased B - unused diode
C - Forward biased C - unbiased C - Reverse biased C - Forward biased

The following are the graphs of potential barrier versus width of the depletion region for a p-n junction diode.

COMEDK 2024 Evening Shift Physics - Semiconductor Devices and Logic Gates Question 1 English

Which of the following is correct?

I II III IV`
A - unbiased diode A - Forward biased diode A - unbiased diode A - unbiased diode
B - Reverse biased B - Reverse biased B - Forward biased B - unused diode
C - Forward biased C - unbiased C - Reverse biased C - Forward biased

Q.29 Correct
Q.29 In-correct
Q.29 Unattempt

Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II

No. Complex ions No. Number of unpaired electrons
(A) $$
\left[\mathrm{Fe} \mathrm{F}_6\right]^{3-}
$$
(P) 0
(B) $$
\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}
$$
(P) 1
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) 5
(D) $$
\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}
$$
(S) 4

Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II

No. Complex ions No. Number of unpaired electrons
(A) $$
\left[\mathrm{Fe} \mathrm{F}_6\right]^{3-}
$$
(P) 0
(B) $$
\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}
$$
(P) 1
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) 5
(D) $$
\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}
$$
(S) 4

Q.34 Correct
Q.34 In-correct
Q.34 Unattempt

Match the names of reactions given in Column I with the appropriate reactions given in Column II.

No. Name of reaction No. Equations representing reactions
(A) Sandmeyer (P) $$
2 \mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl}+\mathrm{Na} \text { (dry ether) } \rightarrow \text { Diphenyl. }
$$
(B) Fittig (Q) $$
\mathrm{CH}_3-\mathrm{CHBr}-\mathrm{CH}_3+\mathrm{AgF} \rightarrow \mathrm{CH}_3-\mathrm{CHF}-\mathrm{CH}_3+\mathrm{AgBr}
$$
(C) Swarts (R) $$
\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{Br}+\mathrm{Nal} \text { ( Acetone) } \rightarrow \mathrm{CH}_3-\mathrm{CH}_2-\mathrm{I}+\mathrm{NaBr}
$$
(D) Finkelstein (S) $$
\mathrm{C}_6 \mathrm{H}_5 \mathrm{~N}_2+\mathrm{Cl}-+\mathrm{Cu}_2 \mathrm{Br}_2 / \mathrm{HBr} \rightarrow \mathrm{C}_6 \mathrm{H}_5 \mathrm{Br}+\mathrm{N}_2
$$

Match the names of reactions given in Column I with the appropriate reactions given in Column II.

No. Name of reaction No. Equations representing reactions
(A) Sandmeyer (P) $$
2 \mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl}+\mathrm{Na} \text { (dry ether) } \rightarrow \text { Diphenyl. }
$$
(B) Fittig (Q) $$
\mathrm{CH}_3-\mathrm{CHBr}-\mathrm{CH}_3+\mathrm{AgF} \rightarrow \mathrm{CH}_3-\mathrm{CHF}-\mathrm{CH}_3+\mathrm{AgBr}
$$
(C) Swarts (R) $$
\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{Br}+\mathrm{Nal} \text { ( Acetone) } \rightarrow \mathrm{CH}_3-\mathrm{CH}_2-\mathrm{I}+\mathrm{NaBr}
$$
(D) Finkelstein (S) $$
\mathrm{C}_6 \mathrm{H}_5 \mathrm{~N}_2+\mathrm{Cl}-+\mathrm{Cu}_2 \mathrm{Br}_2 / \mathrm{HBr} \rightarrow \mathrm{C}_6 \mathrm{H}_5 \mathrm{Br}+\mathrm{N}_2
$$

Q.48 Correct
Q.48 In-correct
Q.48 Unattempt

Match the Vitamins given in Column I with the diseases caused by their deficiency as given in Column II.

Vitamin Deficiency
(A) K (P) Cheilosis
(B) B$$_12$$ (Q) Osteomalacia
(C) B$$_2$$ (R) Permicious Anaemia
(D) D (S) Haemophilia

Match the Vitamins given in Column I with the diseases caused by their deficiency as given in Column II.

Vitamin Deficiency
(A) K (P) Cheilosis
(B) B$$_12$$ (Q) Osteomalacia
(C) B$$_2$$ (R) Permicious Anaemia
(D) D (S) Haemophilia

Q.56 Correct
Q.56 In-correct
Q.56 Unattempt

The following data was recorded for the decomposition of XY compound at 750K

[XY] mol / L Rate of decomposition of XY mol / L s
0.4 $$5.5\times10^{-7}$$
0.8 $$22.0\times10^{-7}$$
1.2 $$49.5\times10^{-7}$$

What is the order of reaction with respect to decomposition of XY?

The following data was recorded for the decomposition of XY compound at 750K

[XY] mol / L Rate of decomposition of XY mol / L s
0.4 $$5.5\times10^{-7}$$
0.8 $$22.0\times10^{-7}$$
1.2 $$49.5\times10^{-7}$$

What is the order of reaction with respect to decomposition of XY?

Q.59 Correct
Q.59 In-correct
Q.59 Unattempt

Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.

No. Complexion No. d orbital configuration of central metal ion.
(A) $$
\left[M n(C N)_6\right]^{4-}
$$
(P) $$
e_g^2 t_{2 g}^3
$$
(B) $$
\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(Q) $$
t_{2 g}^4 e_g^2
$$
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) $$
t_{2 g}^5
$$
(D) $$
\left[\mathrm{MnCl}_4\right]^{2-}
$$
(S) $$
t_{2 g}^5 e_g^2
$$

Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.

No. Complexion No. d orbital configuration of central metal ion.
(A) $$
\left[M n(C N)_6\right]^{4-}
$$
(P) $$
e_g^2 t_{2 g}^3
$$
(B) $$
\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(Q) $$
t_{2 g}^4 e_g^2
$$
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) $$
t_{2 g}^5
$$
(D) $$
\left[\mathrm{MnCl}_4\right]^{2-}
$$
(S) $$
t_{2 g}^5 e_g^2
$$

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