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Which of these hydrogen halides forms salts like KHX2 (where X is a halogen atom)?
Fluorine ion by a process of hydrogen bonding forms the anion [HF2]-. Hence, in the presence of an alkali like KOH, HF forms salt-like compounds like KHF2.
Match the following:
Complex- Addition compounds which do not give all their constituent ions when dissolved in water, individual identity of ions are lost, eg,- [Cu(NH3)4]SO4, LiAIH4.
Lewis acid- Electron deficient species which gain electrons while forming a bond with Lewis bases. eg,-B2H6. Interstitial metal hydrides- f-block hydrides are non-stoichiometric eg, LaHn, etc, where chemical composition is variable eg,- LaH2.87, XbH2.5 etc. Intermediate hydride- Polymeric in nature eg, BeH2 Covalent hydride- Bond forms by sharing of electron. eg, AsH3.
For the laboratory preparation of H2O2,
For the laboratory preparation of H2O2, BaO2 is added to ice cold solution of sulphuric acid. BaO2 + H2SO4 → BaSO4 + H2O2
Which of the following is not correct regarding the electrolytic preparation of H2O2?
H2O2 can be prepared by electrolysis of 50% H2SO4. In this method, hydrogen is liberated at cathode.
The following question has four choices out of which ONLY ONE is correct.
Electrolysis of a hydrochloric acid solution produces
Electrolysis of a hydrochloric acid solution produces oxygen at anode and hydrogen at cathode. The products of electrolysis of dilute solutions of all acids are same as the products of electrolysis of water.
Which of the following processes is not used for concentration of hydrogen peroxide?
Sublimation is not used for concentration of hydrogen peroxide. H2O2 does not sublime, it decomposes at a temperature below its boiling point.
On shaking H2O2 with acidified potassium dichromate and ether, ethereal layer becomes
To very dilute hydrogen peroxide is added a dilute solution of potassium dichromate acidified with sulphuric acid. The solution is rapidly shaken with ether, which floats to the surface with a beautiful blue colour. An unstable perchromic acid is formed, which dissolves in ether to form a blue liquid.
O2F2 molecule resembles H2O2 in
O2F2 molecule resembles H2O2 in structure.
When hydrogen peroxide is added to an acidified solution of potassium dichromate, a blue colour is produced due to the formation of
When hydrogen peroxide is added to an acidified solution of potassium dichromate (or any other Cr (VI) species), a very complicated reaction occurs. The product depends on the pH and the concentration of Cr (VI) ion. Cr2O72- + 2H+ + 4H2O2 → 2CrO(O2)2 + 5H2O A deep blue-violet coloured peroxo compound is formed. Thereafter the solution turns olive green as CrO5 decomposes to form Cr2O3.
Which of the following is not a method of commercial production of dihydrogen?
Reaction of impure Zn with dil. HCl is not used for commercial production of dihydrogen due to low yield.
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