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Hydrogen Test - 1
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Hydrogen Test - 1
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  • Question 1/10
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    Which of these hydrogen halides forms salts like KHX2 (where X is a halogen atom)?

    Solutions

    Fluorine ion by a process of hydrogen bonding forms the anion [HF2]-. Hence, in the presence of an alkali like KOH, HF forms salt-like compounds like KHF2.

     

  • Question 2/10
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    Match the following:

    List - I (Hydride) List - II (Type of Hydride)
    A. BeH2 1. Complex
    B. AsH3 2. Lewis acid
    C. B2H6 3. Interstitial
    D. LaH3 4. Covalent
    E. LiAlH4 5. Intermediate
      6. Ionic
    Solutions

    Complex- Addition compounds which do not give all their constituent ions when dissolved in water, individual identity of ions are lost,
    eg,- [Cu(NH3)4]SO4, LiAIH4.

    Lewis acid- Electron deficient species which gain electrons while forming a bond with Lewis bases. eg,-B2H6.
    Interstitial metal hydrides- f-block hydrides are non-stoichiometric eg, LaHn, etc, where chemical composition is variable eg,- LaH2.87, XbH2.5 etc.
    Intermediate hydride- Polymeric in nature eg, BeH2
    Covalent hydride- Bond forms by sharing of electron. eg, AsH3.

     

  • Question 3/10
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    For the laboratory preparation of H2O2,

    Solutions

    For the laboratory preparation of H2O2, BaO2 is added to ice cold solution of sulphuric acid.
    BaO2 + H2SO4 →  BaSO4 + H2O2

     

  • Question 4/10
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    Which of the following is not correct regarding the electrolytic preparation of H2O2?

    Solutions

    H2O2 can be prepared by electrolysis of 50% H2SO4. In this method, hydrogen is liberated at cathode.

     

  • Question 5/10
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    The following question has four choices out of which ONLY ONE is correct.

    Electrolysis of a hydrochloric acid solution produces

    Solutions

    Electrolysis of a hydrochloric acid solution produces oxygen at anode and hydrogen at cathode.
    The products of electrolysis of dilute solutions of all acids are same as the products of electrolysis of water.

     

  • Question 6/10
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    Which of the following processes is not used for concentration of hydrogen peroxide?

    Solutions

    Sublimation is not used for concentration of hydrogen peroxide. H2O2 does not sublime, it decomposes at a temperature below its boiling point.

     

  • Question 7/10
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    On shaking H2O2 with acidified potassium dichromate and ether, ethereal layer becomes

    Solutions

    To very dilute hydrogen peroxide is added a dilute solution of potassium dichromate acidified with sulphuric acid. The solution is rapidly shaken with ether, which floats to the surface with a beautiful blue colour. An unstable perchromic acid is formed, which dissolves in ether to form a blue liquid.

     

  • Question 8/10
    1 / -0

    O2F2 molecule resembles H2O2 in

    Solutions

    O2F2 molecule resembles H2O2 in structure.

     

  • Question 9/10
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    When hydrogen peroxide is added to an acidified solution of potassium dichromate, a blue colour is produced due to the formation of

    Solutions

    When hydrogen peroxide is added to an acidified solution of potassium dichromate (or any other Cr (VI) species), a very complicated reaction occurs. The product depends on the pH and the concentration of Cr (VI) ion.
    Cr2O72- + 2H+ + 4H2O→ 2CrO(O2)2 + 5H2O
    A deep blue-violet coloured peroxo compound is formed.
    Thereafter the solution turns olive green as CrO5 decomposes to form Cr2O3.

     

  • Question 10/10
    1 / -0

    The following question has four choices out of which ONLY ONE is correct.

    Which of the following is not a method of commercial production of dihydrogen?

    Solutions

    Reaction of impure Zn with dil. HCl is not used for commercial production of dihydrogen due to low yield.

     

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