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Chemistry Test - 51
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Chemistry Test - 51
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  • Question 1/10
    1 / -0

    Match List-I with List-II.

    List-I  List-II
    A. Sucrose (i) β-D-galactose and βD glucose
    B. Lactose (ii) α-D-glucose and β-D-fructose
    C. Maltose (iii)α-D-glucose and α-D-glucose

    Choose the correct answer from the options given below.

    Solutions

    Sucrose (cane sugar), lactose (milk sugar) and maltose are disaccharides in which two monosaccharides are hold together by a glycosidic linkage.

    (A) In sucrose, C1 of αD - glucose and C2 of βD - fructose are linked together (ii).

    (B) In lactose, C1 of β - D-galactose and C4 of β-D-glucose are linked together (i).

    (C) In maltose, C1 of α - D-glucose is linked to C4 of another αD glucose unit (iii).

    So, option (c) is the correct answer.

  • Question 2/10
    1 / -0

    Which of the following is incorrect for primary amines?

    Solutions

    Aryl amines react with nitrous acid to produce diazonium salts.

  • Question 3/10
    1 / -0

    Stephen's reduction converts ethane nitrile into:

    Solutions

    Stephen's reduction converts ethane nitrile into ethanal or Acetaldehyde.

    When ethane nitrile is treated with Sn/HCl, it undergoes Stephen's reaction to form  Acetaldehyde.

    The reaction is:

    The reaction is more efficient when aromatic nitriles are used rather than aliphatic nitriles. The reaction is a redox reaction and electron-withdrawing substituents can improve the rate of the reaction.

  • Question 4/10
    1 / -0

    Heavy water (D2O) freezes at:

    Solutions

    Heavy water (D2O) freezes at3.8C.

    The freezing point of any liquid is the temperature at which the given liquid freezes. It is the temperature for a particular liquid when the liquid turns into a solid state when it undergoes cooling.The temperature for the heavy water at which it will undergo freezing (i.e., it will start to convert itself into the solid-state) is 3.8C and in the kelvin scale, it is 275.8K.

  • Question 5/10
    1 / -0

    120 g of an organic compound that contains only carbon and hydrogen gives 330 g of CO2 and 270 g of water on complete combustion. The percentage of carbon and hydrogen, respectively are

    Solutions

    CxHy+(x+y4)O2xCO2+y2H2O

    From the reaction,

    Produced CO2=xmol

    and produced H2O=y2 mol

    Given produced CO2=330 g

    moles of CO2=33044=304=x

    Also given produced H2O=270gm

    Moles of H2O=27018=15=y2.

    y=30

    x:y=304:30=1:4

    Formula of the compound =(CH4)n

    Weight of C in (CH4)n=12n

    Weight of H in (CH4)n=4n

    Weight ratio of C and H

    =12n:4n

    =3:1

    % of C=34×100=75

    and % of H=14×100=25

  • Question 6/10
    1 / -0

    At equilibrium, if Kp=1, then:

    Solutions

    At equilibrium, the relation between the free energy of the reaction and equilibrium constant is as follows,

    ΔG=RTlnKp

    If Kp=1 at equilibrium

    ΔG=RTln1

    or ΔG=0

  • Question 7/10
    1 / -0

    For a reaction, A(g)A(l);H=3RT. The correct statement for the reaction is:

    Solutions

  • Question 8/10
    1 / -0

    The pair from the following pairs having both compounds with net non-zero dipole moment is

    Solutions

  • Question 9/10
    1 / -0

    The main product formed in the following reaction is:

    Solutions

    We all know that the hydroxyl group is less reactive than the amine group thus amine group will attack the acetyl chloride group and give acetaminophen commonly called paracetamol.

    The reaction is,

    As we know that the paracetamol is a drug used to treat torment and fever. It is regularly utilized for mellow to direct torment relief. Evidence is blended for its utilization to assuage fever in children. It is frequently sold in the mix with different meds, for example, in numerous cold medications.

    Paracetamol is likewise utilized for serious torment, for example, malignant growth agony and torment after a medical procedure, in the mix with narcotic torment medication. It is ordinarily used either by mouth or rectally, and yet is open by implantation into a vein. Impacts last someplace in the scope of two and four hours.

  • Question 10/10
    1 / -0

    In which of the following does sulphur has the lowest oxidation state?

    Solutions

    (D) H2S

    Let oxidation number of sulphur in H2S be x.

    2+x=0

    x=2

    (A) H2SO4

    Let oxidation number of sulphur in H2SO4 be x.

    2+x4(2)=0

    x=+6

    (B) SO2

    Let oxidation number of sulphur in SO2 be x.

    x+(2×2)=0

    x4=0

    x=+4

    (C)H2SO3

    Let oxidation number of sulphur in H2SO3 be x.

    2+x+(3)(2)=0

    x=4

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