JEE Advanced 2022 : Paper-1

Solution

Q.1 Correct

Q.1 In-correct

Q.1 Unattempt

Considering only the principal values of the inverse trigonometric functions, the value of

α

be a positive real number. Let

f : R \to R

and

g : (α, \infty) \to R

be the functions defined by

f (x) = \sin (\frac{π x}{12}) and g (x) = \frac{2 \log_{e} (\sqrt{x} - \sqrt{α})}{\log_{e} (e^{\sqrt{x}} - e^{\sqrt{α}})} .

Then the value of

lim_{x \to α^{+}} f (g (x))

Let

α

be a positive real number. Let

f : R \to R

and

g : (α, \infty) \to R

be the functions defined by

f (x) = \sin (\frac{π x}{12}) and g (x) = \frac{2 \log_{e} (\sqrt{x} - \sqrt{α})}{\log_{e} (e^{\sqrt{x}} - e^{\sqrt{α}})} .

Then the value of

lim_{x \to α^{+}} f (g (x))

Q.3 Correct

Q.3 In-correct

Q.3 Unattempt

In a study about a pandemic, data of 900 persons was collected. It was found that

190 persons had symptom of fever,

220 persons had symptom of cough,

220 persons had symptom of breathing problem,

330 persons had symptom of fever or cough or both,

350 persons had symptom of cough or breathing problem or both,

340 persons had symptom of fever or breathing problem or both,

30 persons had all three symptoms (fever, cough and breathing problem).

If a person is chosen randomly from these 900 persons, then the probability that the person has at most one symptom is ____________.

z

be a complex number with a non-zero imaginary part. If

\frac{2 + 3 z + 4 z^{2}}{2 - 3 z + 4 z^{2}}

is a real number, then the value of

| z |^{2}

is _________.

Let

z

be a complex number with a non-zero imaginary part. If

\frac{2 + 3 z + 4 z^{2}}{2 - 3 z + 4 z^{2}}

is a real number, then the value of

| z |^{2}

\bar{z}

denote the complex conjugate of a complex number

z

and let

i = \sqrt{- 1}

. In the set of complex numbers, the number of distinct roots of the equation

\bar{z} - z^{2} = i (\bar{z} + z^{2})

is _________.

Let

\bar{z}

denote the complex conjugate of a complex number

z

and let

i = \sqrt{- 1}

. In the set of complex numbers, the number of distinct roots of the equation

\bar{z} - z^{2} = i (\bar{z} + z^{2})

l_{1}, l_{2}, \dots, l_{100}

be consecutive terms of an arithmetic progression with common difference

d_{1}

, and let

w_{1}, w_{2}, \dots, w_{100}

be consecutive terms of another arithmetic progression with common difference

d_{2}

, where

d_{1} d_{2} = 10

. For each

i = 1, 2, \dots, 100

, let

R_{i}

be a rectangle with length

l_{i}

, width

w_{i}

and area

A_{i}

. If

A_{51} - A_{50} = 1000

, then the value of

A_{100} - A_{90}

is __________.

Let

l_{1}, l_{2}, \dots, l_{100}

be consecutive terms of an arithmetic progression with common difference

d_{1}

, and let

w_{1}, w_{2}, \dots, w_{100}

be consecutive terms of another arithmetic progression with common difference

d_{2}

, where

d_{1} d_{2} = 10

. For each

i = 1, 2, \dots, 100

, let

R_{i}

be a rectangle with length

l_{i}

, width

w_{i}

and area

A_{i}

. If

A_{51} - A_{50} = 1000

, then the value of

A_{100} - A_{90}

The number of 4-digit integers in the closed interval [2022, 4482] formed by using the digits

0, 2, 3, 4, 6, 7

is _________.

The number of 4-digit integers in the closed interval [2022, 4482] formed by using the digits

0, 2, 3, 4, 6, 7

A B C

be the triangle with

A B = 1, A C = 3

and

∠ B A C = \frac{π}{2}

. If a circle of radius

r > 0

touches the sides

A B, A C

and also touches internally the circumcircle of the triangle

A B C

, then the value of

r

is __________ .

Let

A B C

be the triangle with

A B = 1, A C = 3

and

∠ B A C = \frac{π}{2}

. If a circle of radius

r > 0

touches the sides

A B, A C

and also touches internally the circumcircle of the triangle

A B C

, then the value of

r

Consider the equation

$\int_{1}^{e} \frac{{(\log_{e} x)}^{1 / 2}}{x {(a - {(\log_{e} x)}^{3 / 2})}^{2}} d x = 1, a \in (- \infty, 0) \cup (1, \infty)$

Which of the following statements is/are TRUE?

Consider the equation

$\int_{1}^{e} \frac{{(\log_{e} x)}^{1 / 2}}{x {(a - {(\log_{e} x)}^{3 / 2})}^{2}} d x = 1, a \in (- \infty, 0) \cup (1, \infty)$

Which of the following statements is/are TRUE?

Q.10 Correct

Q.10 In-correct

Q.10 Unattempt

Let $a_{1}, a_{2}, a_{3}, \dots$ be an arithmetic progression with $a_{1} = 7$ and common difference 8. Let $T_{1}, T_{2}, T_{3}, \dots$ be such that $T_{1} = 3$ and $T_{n + 1} - T_{n} = a_{n}$ for $n \geq 1$ . Then, which of the following is/are TRUE ?

P_{1}

and

P_{2}

be two planes given by

\begin{aligned} P_{1} : 10 x + 15 y + 12 z - 60 = 0 \\ P_{2} : - 2 x + 5 y + 4 z - 20 = 0 \end{aligned}

Which of the following straight lines can be an edge of some tetrahedron whose two faces lie on

P_{1}

and

P_{2}

Let

P_{1}

and

P_{2}

be two planes given by

\begin{aligned} P_{1} : 10 x + 15 y + 12 z - 60 = 0 \\ P_{2} : - 2 x + 5 y + 4 z - 20 = 0 \end{aligned}

Which of the following straight lines can be an edge of some tetrahedron whose two faces lie on

P_{1}

and

P_{2}

S

be the reflection of a point

Q

with respect to the plane given by

\vec{r} = - (t + p) \hat{ı} + t \hat{ȷ} + (1 + p) \hat{k}

where

t, p

are real parameters and

\hat{ı}, \hat{ȷ}, \hat{k}

are the unit vectors along the three positive coordinate axes. If the position vectors of

Q

and

S

are

10 \hat{ı} + 15 \hat{ȷ} + 20 \hat{k}

and

α \hat{ı} + β \hat{ȷ} + γ \hat{k}

respectively, then which of the following is/are TRUE ?

Let

S

be the reflection of a point

Q

with respect to the plane given by

\vec{r} = - (t + p) \hat{ı} + t \hat{ȷ} + (1 + p) \hat{k}

where

t, p

are real parameters and

\hat{ı}, \hat{ȷ}, \hat{k}

are the unit vectors along the three positive coordinate axes. If the position vectors of

Q

and

S

are

10 \hat{ı} + 15 \hat{ȷ} + 20 \hat{k}

and

α \hat{ı} + β \hat{ȷ} + γ \hat{k}

respectively, then which of the following is/are TRUE ?

Q.13 Correct

Q.13 In-correct

Q.13 Unattempt

Consider the parabola $y^{2} = 4 x$ . Let $S$ be the focus of the parabola. A pair of tangents drawn to the parabola from the point $P = (- 2, 1)$ meet the parabola at $P_{1}$ and $P_{2}$ . Let $Q_{1}$ and $Q_{2}$ be points on the lines $S P_{1}$ and $S P_{2}$ respectively such that $P Q_{1}$ is perpendicular to $S P_{1}$ and $P Q_{2}$ is perpendicular to $S P_{2}$ . Then, which of the following is/are TRUE?

Q.14 Correct

Q.14 In-correct

Q.14 Unattempt

Let $| M |$ denote the determinant of a square matrix $M$ . Let $g : [0, \frac{π}{2}] \to R$ be the function defined by

$g (θ) = \sqrt{f (θ) - 1} + \sqrt{f (\frac{π}{2} - θ) - 1}$

where

$f (θ) = \frac{1}{2} | \begin{array}{ccc} 1 & \sin θ & 1 \\ - \sin θ & 1 & \sin θ \\ - 1 & - \sin θ & 1 \end{array} | + | \begin{array}{ccc} \sin π & \cos (θ + \frac{π}{4}) & \tan (θ - \frac{π}{4}) \\ \sin (θ - \frac{π}{4}) & - \cos \frac{π}{2} & \log_{e} (\frac{4}{π}) \\ \cot (θ + \frac{π}{4}) & \log_{e} (\frac{π}{4}) & \tan π \end{array} | .$

Let $p (x)$ be a quadratic polynomial whose roots are the maximum and minimum values of the function $g (θ)$ , and $p (2) = 2 - \sqrt{2}$ . Then, which of the following is/are TRUE ?

Let $| M |$ denote the determinant of a square matrix $M$ . Let $g : [0, \frac{π}{2}] \to R$ be the function defined by

$g (θ) = \sqrt{f (θ) - 1} + \sqrt{f (\frac{π}{2} - θ) - 1}$

where

Let $p (x)$ be a quadratic polynomial whose roots are the maximum and minimum values of the function $g (θ)$ , and $p (2) = 2 - \sqrt{2}$ . Then, which of the following is/are TRUE ?

Q.15 Correct

Q.15 In-correct

Q.15 Unattempt

Consider the following lists:

List-I	List-II
(I) ${x \in [- \frac{2 π}{3}, \frac{2 π}{3}] : \cos x + \sin x = 1}$	(P) has two elements
(II) ${x \in [- \frac{5 π}{18}, \frac{5 π}{18}] : \sqrt{3} \tan 3 x = 1}$	(Q) has three elements
(III) ${x \in [- \frac{6 π}{5}, \frac{6 π}{5}] : 2 \cos (2 x) = \sqrt{3}}$	(R) has four elements
(IV) ${x \in [- \frac{7 π}{4}, \frac{7 π}{4}] : \sin x - \cos x = 1}$	(S) has five elements
	(T) has six elements

Consider the following lists:

List-I	List-II
(I) ${x \in [- \frac{2 π}{3}, \frac{2 π}{3}] : \cos x + \sin x = 1}$	(P) has two elements
(II) ${x \in [- \frac{5 π}{18}, \frac{5 π}{18}] : \sqrt{3} \tan 3 x = 1}$	(Q) has three elements
(III) ${x \in [- \frac{6 π}{5}, \frac{6 π}{5}] : 2 \cos (2 x) = \sqrt{3}}$	(R) has four elements
(IV) ${x \in [- \frac{7 π}{4}, \frac{7 π}{4}] : \sin x - \cos x = 1}$	(S) has five elements
	(T) has six elements

Q.16 Correct

Q.16 In-correct

Q.16 Unattempt

Two players, $P_{1}$ and $P_{2}$ , play a game against each other. In every round of the game, each player rolls a fair die once, where the six faces of the die have six distinct numbers. Let $x$ and $y$ denote the readings on the die rolled by $P_{1}$ and $P_{2}$ , respectively. If $x > y$ , then $P_{1}$ scores 5 points and $P_{2}$ scores 0 point. If $x = y$ , then each player scores 2 points. If $x < y$ , then $P_{1}$ scores 0 point and $P_{2}$ scores 5 points. Let $X_{i}$ and $Y_{i}$ be the total scores of $P_{1}$ and $P_{2}$ , respectively, after playing the $i^{th}$ round.

List-I	List-II

(I) Probability of (X₂≥ Y₂) is	(P) 3/8
(II) Probability of (X₂> Y₂) is	(Q) 11/16
(III) Probability of (X₃= Y₃) is	(R) 5/16
(IV) Probability of (X₃> Y₃) is	(S) 355/864
	(T) 77/432

List-I	List-II
(I) Probability of $(X_{2} \geq Y_{2})$ is	(P) $\frac{3}{8}$
(II) Probability of $(X_{2} > Y_{2})$ is	(Q) $\frac{11}{16}$
(III) Probability of $(X_{3} = Y_{3})$ is	(R) $\frac{5}{16}$
(IV) Probability of

Q.17 Correct

Q.17 In-correct

Q.17 Unattempt

Let $p, q, r$ be nonzero real numbers that are, respectively, the $10^{th}, 100^{th}$ and $1000^{th}$ terms of a harmonic progression. Consider the system of linear equations

$\begin{matrix} x + y + z = 1 \\ 10 x + 100 y + 1000 z = 0 \\ q r x + p r y + p q z = 0 \end{matrix}$

List-I	List-II
(I) If $\frac{q}{r} = 10$ , then the system of linear equations has	(P) $x = 0, y = \frac{10}{9}, z = - \frac{1}{9}$ as a solution
(II) If $\frac{p}{r} \neq 100$ , then the system of linear equations has	(Q) $x = \frac{10}{9}, y = - \frac{1}{9}, z = 0$ as a solution
(III) If $\frac{p}{q} \neq 10$ , then the system of linear equations has	(R) infinitely many solutions
(IV) If $\frac{p}{q} = 10$ , then the system of linear equations has	(S) no solution
	(T) at least one solution

Let $p, q, r$ be nonzero real numbers that are, respectively, the $10^{th}, 100^{th}$ and $1000^{th}$ terms of a harmonic progression. Consider the system of linear equations

$\begin{matrix} x + y + z = 1 \\ 10 x + 100 y + 1000 z = 0 \\ q r x + p r y + p q z = 0 \end{matrix}$

List-I	List-II
(I) If $\frac{q}{r} = 10$ , then the system of linear equations has	(P) $x = 0, y = \frac{10}{9}, z = - \frac{1}{9}$ as a solution
(II) If $\frac{p}{r} \neq 100$ , then the system of linear equations has	(Q) $x = \frac{10}{9}, y = - \frac{1}{9}, z = 0$ as a solution
(III) If $\frac{p}{q} \neq 10$ , then the system of linear equations has	(R) infinitely many solutions
(IV) If $\frac{p}{q} = 10$ , then the system of linear equations has	(S) no solution
	(T) at least one solution

Q.18 Correct

Q.18 In-correct

Q.18 Unattempt

Consider the ellipse

Let 𝐻(𝛼, 0), 0 < 𝛼 < 2, be a point. A straight line drawn through 𝐻 parallel to the 𝑦-axis crosses the ellipse and its auxiliary circle at points 𝐸 and 𝐹 respectively, in the first quadrant. The tangent to the ellipse at the point 𝐸 intersects the positive 𝑥-axis at a point 𝐺. Suppose the straight line joining 𝐹 and the origin makes an angle 𝜙 with the positive 𝑥-axis.

Consider the ellipse

Q.1 Correct

Q.1 In-correct

Q.1 Unattempt

$2 mol of Hg (g)$ is combusted in a fixed volume bomb calorimeter with excess of $O_{2}$ at $298 K$ and 1 atm into $HgO (s)$ . During the reaction, temperature increases from $298.0 K$ to $312.8 K$ . If heat capacity of the bomb calorimeter and enthalpy of formation of $Hg (g)$ are $20.00 kJ K^{- 1}$ and $61.32 kJ$ ${mol}^{- 1}$ at $298 K$ , respectively, the calculated standard molar enthalpy of formation of $HgO (s)$ at 298 $K$ is $X kJ {mol}^{- 1}$ . The value of $| X |$ is _________ .

[Given: Gas constant R=8.3 J K^-1mol^-1]

Q.2 Correct

Q.2 In-correct

Q.2 Unattempt

The reduction potential $(E^{0}$ , in $V)$ of ${MnO}_{4}^{-} (aq) / Mn (s)$ is __________.

[Given: $E_{({MnO}_{4}^{-} (aq) / {MnO}_{2} (s))}^{0} = 1.68 V; E_{({MnO}_{2} (s) / {Mn}^{2 +} (aq))}^{0} = 1.21 V; E_{({Mn}^{2 +} (aq) / Mn (s))}^{0} = - 1.03 V$ ]

The reduction potential $(E^{0}$ , in $V)$ of ${MnO}_{4}^{-} (aq) / Mn (s)$ is __________.

[Given: $E_{({MnO}_{4}^{-} (aq) / {MnO}_{2} (s))}^{0} = 1.68 V; E_{({MnO}_{2} (s) / {Mn}^{2 +} (aq))}^{0} = 1.21 V; E_{({Mn}^{2 +} (aq) / Mn (s))}^{0} = - 1.03 V$ ]

Q.3 Correct

Q.3 In-correct

Q.3 Unattempt

A solution is prepared by mixing $0.01 mol$ each of $H_{2} {CO}_{3}, {NaHCO}_{3}, {Na}_{2} {CO}_{3}$ , and $NaOH$ in $100 mL$ of water. $p H$ of the resulting solution is _________.

[Given: $p K_{a 1}$ and $p K_{a 2}$ of $H_{2} {CO}_{3}$ are $6.37$ and 10.32, respectively; $\log 2 = 0.30$ ]

A solution is prepared by mixing $0.01 mol$ each of $H_{2} {CO}_{3}, {NaHCO}_{3}, {Na}_{2} {CO}_{3}$ , and $NaOH$ in $100 mL$ of water. $p H$ of the resulting solution is _________.

[Given: $p K_{a 1}$ and $p K_{a 2}$ of $H_{2} {CO}_{3}$ are $6.37$ and 10.32, respectively; $\log 2 = 0.30$ ]

Q.4 Correct

Q.4 In-correct

Q.4 Unattempt

The treatment of an aqueous solution of $3.74 g$ of $Cu {({NO}_{3})}_{2}$ with excess KI results in a brown solution along with the formation of a precipitate. Passing $H_{2} S$ through this brown solution gives another precipitate $X$ . The amount of $X$ (in $g$ ) is ___________.

[Given: Atomic mass of $H = 1, N = 14, O = 16, S = 32, K = 39, Cu = 63, I = 127$ ]

Q.5 Correct

Q.5 In-correct

Q.5 Unattempt

Dissolving $1.24 g$ of white phosphorous in boiling $NaOH$ solution in an inert atmosphere gives a gas $Q$ . The amount of ${CuSO}_{4}$ (in g) required to completely consume the gas $Q$ is _________.

[Given: Atomic mass of $H = 1, O = 16, Na = 23, P = 31, S = 32, Cu = 63$ ]

Dissolving $1.24 g$ of white phosphorous in boiling $NaOH$ solution in an inert atmosphere gives a gas $Q$ . The amount of ${CuSO}_{4}$ (in g) required to completely consume the gas $Q$ is _________.

[Given: Atomic mass of $H = 1, O = 16, Na = 23, P = 31, S = 32, Cu = 63$ ]

Q.6 Correct

Q.6 In-correct

Q.6 Unattempt

Consider the following reaction.

On estimation of bromine in $1.00 g$ of $R$ using Carius method, the amount of $AgBr$ formed (in $g$ ) is ___________.

[Given: Atomic mass of $H = 1, C = 12, O = 16, P = 31, Br = 80, Ag = 108]$

Consider the following reaction.

On estimation of bromine in $1.00 g$ of $R$ using Carius method, the amount of $AgBr$ formed (in $g$ ) is ___________.

[Given: Atomic mass of $H = 1, C = 12, O = 16, P = 31, Br = 80, Ag = 108]$

Q.7 Correct

Q.7 In-correct

Q.7 Unattempt

The weight percentage of hydrogen in $Q$ , formed in the following reaction sequence, is ________.

[Given: Atomic mass of $H = 1, C = 12, N = 14, O = 16, S = 32, Cl = 35$ ]

The weight percentage of hydrogen in $Q$ , formed in the following reaction sequence, is ________.

[Given: Atomic mass of $H = 1, C = 12, N = 14, O = 16, S = 32, Cl = 35$ ]

Q.8 Correct

Q.8 In-correct

Q.8 Unattempt

If the reaction sequence given below is carried out with 15 moles of acetylene, the amount of the product $D$ formed (in $g$ ) is ___________ .

The yields of $A, B, C$ and $D$ are given in parentheses.

[Given: Atomic mass of $H = 1, C = 12, O = 16, Cl = 35$ ]

If the reaction sequence given below is carried out with 15 moles of acetylene, the amount of the product $D$ formed (in $g$ ) is ___________ .

The yields of $A, B, C$ and $D$ are given in parentheses.

[Given: Atomic mass of $H = 1, C = 12, O = 16, Cl = 35$ ]

Q.9 Correct

Q.9 In-correct

Q.9 Unattempt

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap of two

2 p_{z}

orbitals is(are)

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap of two

2 p_{z}

The correct option(s) related to adsorption processes is(are)

Q.11 Correct

Q.11 In-correct

Q.11 Unattempt

The electrochemical extraction of aluminum from bauxite ore involves

Q.12 Correct

Q.12 In-correct

Q.12 Unattempt

The treatment of galena with

{HNO}_{3}

produces a gas that is

The treatment of galena with

{HNO}_{3}

produces a gas that is

Q.13 Correct

Q.13 In-correct

Q.13 Unattempt

Considering the reaction sequence given below, the correct statement(s) is(are)

Q.14 Correct

Q.14 In-correct

Q.14 Unattempt

Considering the following reaction sequence,

the correct option(s) is(are)

Considering the following reaction sequence,

the correct option(s) is(are)

Q.15 Correct

Q.15 In-correct

Q.15 Unattempt

Match the rate expressions in LIST-I for the decomposition of $X$ with the corresponding profiles provided in LIST-II. $X_{s}$ and $k$ are constants having appropriate units.

List-I	List-II
(I) rate $= \frac{k [X]}{X_{s} + [X]}$ under all possible initial concentrations of $X$	(P)
(II) rate $= \frac{k [X]}{X_{s} + [X]}$ where initial concentrations of $X$ are much less than $X_{s}$	(Q)
(III) rate $= \frac{k [X]}{X_{s} + [X]}$ where initial concentrations of $X$ are much higher than $X_{s}$	(R)
(IV) rate $= \frac{k [X]^{2}}{X_{s} + [X]}$ where initial concentration of $X$ is much higher than $X_{s}$	(S)
	(T)

Match the rate expressions in LIST-I for the decomposition of $X$ with the corresponding profiles provided in LIST-II. $X_{s}$ and $k$ are constants having appropriate units.

List-I	List-II
(I) rate $= \frac{k [X]}{X_{s} + [X]}$ under all possible initial concentrations of $X$	(P)
(II) rate $= \frac{k [X]}{X_{s} + [X]}$ where initial concentrations of $X$ are much less than $X_{s}$	(Q)
(III) rate $= \frac{k [X]}{X_{s} + [X]}$ where initial concentrations of $X$ are much higher than $X_{s}$	(R)
(IV) rate $= \frac{k [X]^{2}}{X_{s} + [X]}$ where initial concentration of $X$ is much higher than $X_{s}$	(S)
	(T)

Q.16 Correct

Q.16 In-correct

Q.16 Unattempt

LIST-I contains compounds and LIST-II contains reactions

List-I	List-II
(I) $H_{2} O_{2}$	(P) $Mg {({HCO}_{3})}_{2} + Ca (OH)_{2} \to$
(II) $Mg (OH)_{2}$	(Q) ${BaO}_{2} + H_{2} {SO}_{4} \to$
(III) ${BaCl}_{2}$	(R) $Ca (OH)_{2} + {MgCl}_{2} \to$
(IV) ${CaCO}_{3}$	(S) ${BaO}_{2} + HCl \to$
	(T) $Ca {({HCO}_{3})}_{2} + Ca (OH)_{2} \to$

Match each compound in LIST-I with its formation reaction(s) in LIST-II, and choose the correct option

LIST-I contains compounds and LIST-II contains reactions

List-I	List-II
(I) $H_{2} O_{2}$	(P) $Mg {({HCO}_{3})}_{2} + Ca (OH)_{2} \to$
(II) $Mg (OH)_{2}$	(Q) ${BaO}_{2} + H_{2} {SO}_{4} \to$
(III) ${BaCl}_{2}$	(R) $Ca (OH)_{2} + {MgCl}_{2} \to$
(IV) ${CaCO}_{3}$	(S) ${BaO}_{2} + HCl \to$
	(T) $Ca {({HCO}_{3})}_{2} + Ca (OH)_{2} \to$

Match each compound in LIST-I with its formation reaction(s) in LIST-II, and choose the correct option

Q.17 Correct

Q.17 In-correct

Q.17 Unattempt

LIST-I contains metal species and LIST-II contains their properties.

List-I	List-II
(I) ${[Cr (CN)_{6}]}^{4 -}$	(P) $t_{2 g}$ orbitals contain 4 electrons
(II) ${[{RuCl}_{6}]}^{2 -}$	(Q) $μ$ (spin-only $) = 4.9 BM$
(III) ${[Cr {(H_{2} O)}_{6}]}^{2 +}$	(R) low spin complex ion
(IV) ${[Fe {(H_{2} O)}_{6}]}^{2 +}$	(S) metal ion in $4 +$ oxidation state
	(T) $d^{4}$ species

[Given: Atomic number of $Cr = 24, Ru = 44, Fe = 26$ ]

Match each metal species in LIST-I with their properties in LIST-II, and choose the correct option

LIST-I contains metal species and LIST-II contains their properties.

List-I	List-II
(I) ${[Cr (CN)_{6}]}^{4 -}$	(P) $t_{2 g}$ orbitals contain 4 electrons
(II) ${[{RuCl}_{6}]}^{2 -}$	(Q) $μ$ (spin-only $) = 4.9 BM$
(III) ${[Cr {(H_{2} O)}_{6}]}^{2 +}$	(R) low spin complex ion
(IV) ${[Fe {(H_{2} O)}_{6}]}^{2 +}$	(S) metal ion in $4 +$ oxidation state
	(T) $d^{4}$ species

[Given: Atomic number of $Cr = 24, Ru = 44, Fe = 26$ ]

Match each metal species in LIST-I with their properties in LIST-II, and choose the correct option

Q.18 Correct

Q.18 In-correct

Q.18 Unattempt

Match the compounds in LIST-I with the observations in LIST-II, and choose the correct option.

List-I	List-II
(I) Aniline	(P) Sodium fusion extract of the compound on boiling with ${FeSO}_{4}$ , followed by acidification with conc. $H_{2} {SO}_{4}$ , gives Prussian blue color.
(II) $o$ -Cresol	(Q) Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
(III) Cysteine	(R) Addition of the compound to a saturated solution of ${NaHCO}_{3}$ results in effervescence.
(IV) Caprolactam	(S) The compound reacts with bromine water to give a white precipitate.
	(T) Treating the compound with neutral ${FeCl}_{3}$ solution produces violet color.

Match the compounds in LIST-I with the observations in LIST-II, and choose the correct option.

List-I	List-II
(I) Aniline	(P) Sodium fusion extract of the compound on boiling with ${FeSO}_{4}$ , followed by acidification with conc. $H_{2} {SO}_{4}$ , gives Prussian blue color.
(II) $o$ -Cresol	(Q) Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
(III) Cysteine	(R) Addition of the compound to a saturated solution of ${NaHCO}_{3}$ results in effervescence.
(IV) Caprolactam	(S) The compound reacts with bromine water to give a white precipitate.
	(T) Treating the compound with neutral ${FeCl}_{3}$ solution produces violet color.

Q.1 Correct

Q.1 In-correct

Q.1 Unattempt

Two spherical stars $A$ and $B$ have densities $ρ_{A}$ and $ρ_{B}$ , respectively. $A$ and $B$ have the same radius, and their masses $M_{A}$ and $M_{B}$ are related by $M_{B} = 2 M_{A}$ . Due to an interaction process, star $A$ loses some of its mass, so that its radius is halved, while its spherical shape is retained, and its density remains $ρ_{A}$ . The entire mass lost by $A$ is deposited as a thick spherical shell on $B$ with the density of the shell being $ρ_{A}$ . If $v_{A}$ and $v_{B}$ are the escape velocities from $A$ and $B$ after the interaction process, the ratio $\frac{v_{B}}{v_{A}} = \sqrt{\frac{10 n}{15^{1 / 3}}}$ . The value of $n$ is __________ .

Q.2 Correct

Q.2 In-correct

Q.2 Unattempt

The minimum kinetic energy needed by an alpha particle to cause the nuclear reaction

_{7}^{16} N +

_{2}^{4} He \to_{1}^{1} H +_{8}^{19} O

in a laboratory frame is

n

(in

M e V

. Assume that

_{7}^{16} N

is at rest in the laboratory frame. The masses of

_{7}^{16} N,_{2}^{4} He,_{1}^{1} H

and

_{8}^{19} O

can be taken to be

16.006 u, 4.003 u, 1.008 u

and

19.003 u

, respectively, where

1 u = 930 {MeVc}^{- 2}

. The value of

n

is ________ .

The minimum kinetic energy needed by an alpha particle to cause the nuclear reaction

_{7}^{16} N +

_{2}^{4} He \to_{1}^{1} H +_{8}^{19} O

in a laboratory frame is

n

(in

M e V

. Assume that

_{7}^{16} N

is at rest in the laboratory frame. The masses of

_{7}^{16} N,_{2}^{4} He,_{1}^{1} H

and

_{8}^{19} O

can be taken to be

16.006 u, 4.003 u, 1.008 u

and

19.003 u

, respectively, where

1 u = 930 {MeVc}^{- 2}

. The value of

n

In the following circuit $C_{1} = 12 μ F, C_{2} = C_{3} = 4 μ F$ and $C_{4} = C_{5} = 2 μ F$ . The charge stored in $C_{3}$ is ____________ $μ C$ .

Q.4 Correct

Q.4 In-correct

Q.4 Unattempt

A rod of length $2 cm$ makes an angle $\frac{2 π}{3} rad$ with the principal axis of a thin convex lens. The lens has a focal length of $10 cm$ and is placed at a distance of $\frac{40}{3} cm$ from the object as shown in the figure. The height of the image is $\frac{30 \sqrt{3}}{13} cm$ and the angle made by it with respect to the principal axis is $α$ rad. The value of $α$ is $\frac{π}{n} r a d$ , where $n$ is __________ .

t = 0

, a disk of radius

1 m

starts to roll without slipping on a horizontal plane with an angular acceleration of

α = \frac{2}{3} rad s^{- 2}

. A small stone is stuck to the disk. At

t = 0

, it is at the contact point of the disk and the plane. Later, at time

t = \sqrt{π} s

, the stone detaches itself and flies off tangentially from the disk. The maximum height (in

m

) reached by the stone measured from the plane is

\frac{1}{2} + \frac{x}{10}

. The value of

x

is ____________ , [Take

g = 10 m s^{- 2}

At time

t = 0

, a disk of radius

1 m

starts to roll without slipping on a horizontal plane with an angular acceleration of

α = \frac{2}{3} rad s^{- 2}

. A small stone is stuck to the disk. At

t = 0

, it is at the contact point of the disk and the plane. Later, at time

t = \sqrt{π} s

, the stone detaches itself and flies off tangentially from the disk. The maximum height (in

m

) reached by the stone measured from the plane is

\frac{1}{2} + \frac{x}{10}

. The value of

x

is ____________ , [Take

g = 10 m s^{- 2}

Q.6 Correct

Q.6 In-correct

Q.6 Unattempt

A solid sphere of mass $1 kg$ and radius $1 m$ rolls without slipping on a fixed inclined plane with an angle of inclination $θ = 30^{\circ}$ from the horizontal. Two forces of magnitude $1 N$ each, parallel to the incline, act on the sphere, both at distance $r = 0.5 m$ from the center of the sphere, as shown in the figure. The acceleration of the sphere down the plane is _________ $m s^{- 2} . ($ Take $g = 10 m s^{- 2}$ )

Q.7 Correct

Q.7 In-correct

Q.7 Unattempt

Consider an LC circuit, with inductance

L = 0.1 H

and capacitance

C = 10^{- 3} F

, kept on a plane. The area of the circuit is

1 m^{2}

. It is placed in a constant magnetic field of strength

B_{0}

which is perpendicular to the plane of the circuit. At time

t = 0

, the magnetic field strength starts increasing linearly as

B = B_{0} + β t

with

β = 0.04 {T s}^{- 1}

. The maximum magnitude of the current in the circuit is _________

m A

Consider an LC circuit, with inductance

L = 0.1 H

and capacitance

C = 10^{- 3} F

, kept on a plane. The area of the circuit is

1 m^{2}

. It is placed in a constant magnetic field of strength

B_{0}

which is perpendicular to the plane of the circuit. At time

t = 0

, the magnetic field strength starts increasing linearly as

B = B_{0} + β t

with

β = 0.04 {T s}^{- 1}

. The maximum magnitude of the current in the circuit is _________

m A

Q.8 Correct

Q.8 In-correct

Q.8 Unattempt

A projectile is fired from horizontal ground with speed

v

and projection angle

θ

. When the acceleration due to gravity is

g

, the range of the projectile is

d

. If at the highest point in its trajectory, the projectile enters a different region where the effective acceleration due to gravity is

g^{'} = \frac{g}{0.81}

, then the new range is

d^{'} = n d

. The value of

n

is ___________ .

A projectile is fired from horizontal ground with speed

v

and projection angle

θ

. When the acceleration due to gravity is

g

, the range of the projectile is

d

. If at the highest point in its trajectory, the projectile enters a different region where the effective acceleration due to gravity is

g^{'} = \frac{g}{0.81}

, then the new range is

d^{'} = n d

. The value of

n

A medium having dielectric constant $K > 1$ fills the space between the plates of a parallel plate capacitor. The plates have large area, and the distance between them is $d$ . The capacitor is connected to a battery of voltage $V$ , as shown in Figure (a). Now, both the plates are moved by a distance of $\frac{d}{2}$ from their original positions, as shown in Figure (b).

In the process of going from the configuration depicted in Figure (a) to that in Figure (b), which of the following statement(s) is(are) correct?

Q.10 Correct

Q.10 In-correct

Q.10 Unattempt

The figure shows a circuit having eight resistances of $1 Ω$ each, labelled $R_{1}$ to $R_{8}$ , and two ideal batteries with voltages $ε_{1} = 12 V$ and $ε_{2} = 6 V$ .

Which of the following statement(s) is(are) correct?

The figure shows a circuit having eight resistances of $1 Ω$ each, labelled $R_{1}$ to $R_{8}$ , and two ideal batteries with voltages $ε_{1} = 12 V$ and $ε_{2} = 6 V$ .

Which of the following statement(s) is(are) correct?

Q.11 Correct

Q.11 In-correct

Q.11 Unattempt

An ideal gas of density $ρ = 0.2 kg m^{- 3}$ enters a chimney of height $h$ at the rate of $α =$ $0.8 kg s^{- 1}$ from its lower end, and escapes through the upper end as shown in the figure. The cross-sectional area of the lower end is $A_{1} = 0.1 m^{2}$ and the upper end is $A_{2} = 0.4 m^{2}$ . The pressure and the temperature of the gas at the lower end are $600 Pa$ and $300 K$ , respectively, while its temperature at the upper end is $150 K$ . The chimney is heat insulated so that the gas undergoes adiabatic expansion. Take $g = 10 m s^{- 2}$ and the ratio of specific heats of the gas $γ = 2$ . Ignore atmospheric pressure.

Which of the following statement(s) is(are) correct?

Q.12 Correct

Q.12 In-correct

Q.12 Unattempt

Three plane mirrors form an equilateral triangle with each side of length $L$ . There is a small hole at a distance $l > 0$ from one of the corners as shown in the figure. A ray of light is passed through the hole at an angle $θ$ and can only come out through the same hole. The cross section of the mirror configuration and the ray of light lie on the same plane.

Which of the following statement(s) is(are) correct?

Q.13 Correct

Q.13 In-correct

Q.13 Unattempt

Six charges are placed around a regular hexagon of side length $a$ as shown in the figure. Five of them have charge $q$ , and the remaining one has charge $x$ . The perpendicular from each charge to the nearest hexagon side passes through the center 0 of the hexagon and is bisected by the side.

Which of the following statement(s) is(are) correct in SI units?

Q.14 Correct

Q.14 In-correct

Q.14 Unattempt

The binding energy of nucleons in a nucleus can be affected by the pairwise Coulomb repulsion. Assume that all nucleons are uniformly distributed inside the nucleus. Let the binding energy of a proton be $E_{b}^{p}$ and the binding energy of a neutron be $E_{b}^{n}$ in the nucleus.

Which of the following statement(s) is(are) correct?

Q.15 Correct

Q.15 In-correct

Q.15 Unattempt

A small circular loop of area $A$ and resistance $R$ is fixed on a horizontal $x y$ -plane with the center of the loop always on the axis $\hat{n}$ of a long solenoid. The solenoid has $m$ turns per unit length and carries current $I$ counterclockwise as shown in the figure. The magnetic field due to the solenoid is in $\hat{n}$ direction. List-I gives time dependences of $\hat{n}$ in terms of a constant angular frequency $ω$ . List-II gives the torques experienced by the circular loop at time $t = \frac{π}{6 ω}$ . Let $α = \frac{A^{2} μ_{0}^{2} m^{2} I^{2} ω}{2 R}$ .

Q.16 Correct

Q.16 In-correct

Q.16 Unattempt

List I describes four systems, each with two particles $A$ and $B$ in relative motion as shown in figures. List II gives possible magnitudes of their relative velocities (in $m s^{- 1}$ ) at time $t = \frac{π}{3} s$ .

Q.17 Correct

Q.17 In-correct

Q.17 Unattempt

List I describes thermodynamic processes in four different systems. List II gives the magnitudes (either exactly or as a close approximation) of possible changes in the internal energy of the system due to the process.

Q.18 Correct

Q.18 In-correct

Q.18 Unattempt

List I contains four combinations of two lenses (1 and 2) whose focal lengths (in $cm$ ) are indicated in the figures. In all cases, the object is placed $20 cm$ from the first lens on the left, and the distance between the two lenses is $5 cm$ . List II contains the positions of the final images.

Which one of the following options is correct?