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Solution
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Q.29 Correct
Q.29 In-correct
Q.29 Unattempt
If $\sin A+\sin B=-\frac{21}{65}, \cos A+\cos B=-\frac{27}{65}$ and $\pi
Q.5 Correct
Q.5 In-correct
Q.5 Unattempt

Match the metals in Column II with their characteristic properties given in Column I.

Properties Metals
A. Lanthanoid with low value of $3^{\text {rd }}$ ionisation enthalpy. P V
B. f-Block element with electronic configuration $[R n] 6 d^2 7 s^2$ Q Gd
C. 3 d -series metal whose $\mathrm{M}^{3+}{ }_{(\mathrm{aq})}$ is colourless. R Th
D. 3d-series metal with highest $\Delta \mathrm{H}_{\text {(atomisation) }}$ S Sc

Match the metals in Column II with their characteristic properties given in Column I.

Properties Metals
A. Lanthanoid with low value of $3^{\text {rd }}$ ionisation enthalpy. P V
B. f-Block element with electronic configuration $[R n] 6 d^2 7 s^2$ Q Gd
C. 3 d -series metal whose $\mathrm{M}^{3+}{ }_{(\mathrm{aq})}$ is colourless. R Th
D. 3d-series metal with highest $\Delta \mathrm{H}_{\text {(atomisation) }}$ S Sc

Q.28 Correct
Q.28 In-correct
Q.28 Unattempt

Arrange the following compounds in the decreasing order of the molar conductivities of their aqueous solutions.

A B C D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$

Arrange the following compounds in the decreasing order of the molar conductivities of their aqueous solutions.

A B C D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$

Q.37 Correct
Q.37 In-correct
Q.37 Unattempt

Match the coordination compounds in Column I having the given type of hybridisation of $\mathrm{M}^{\mathrm{n}+}$ ion and magnetic moment as given in Column II.

Coordination compounds Hybridisation & Magnetic nature
A. $\mathrm{Ni}(\mathrm{CO})_4$ P. $\mathrm{sp}^3, \quad \mu=5.92 \mathrm{BM}$
B. $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ Q. $\mathrm{sp}^3, \quad \mu=2.84 \mathrm{BM}$
C. $\left[\mathrm{Ni}(\mathrm{Cl})_4\right]^{2-}$ R. $\mathrm{sp}^3, \quad \mu=0$
D. $\left[\mathrm{MnBr}_4\right]^{2-}$ S. $\mathrm{dsp}^2, \quad \mu=0$

Match the coordination compounds in Column I having the given type of hybridisation of $\mathrm{M}^{\mathrm{n}+}$ ion and magnetic moment as given in Column II.

Coordination compounds Hybridisation & Magnetic nature
A. $\mathrm{Ni}(\mathrm{CO})_4$ P. $\mathrm{sp}^3, \quad \mu=5.92 \mathrm{BM}$
B. $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ Q. $\mathrm{sp}^3, \quad \mu=2.84 \mathrm{BM}$
C. $\left[\mathrm{Ni}(\mathrm{Cl})_4\right]^{2-}$ R. $\mathrm{sp}^3, \quad \mu=0$
D. $\left[\mathrm{MnBr}_4\right]^{2-}$ S. $\mathrm{dsp}^2, \quad \mu=0$

Q.48 Correct
Q.48 In-correct
Q.48 Unattempt

Match the structures in Column I with their correct IUPAC names given in Column II.

Column I Column II
A. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 1 P. 2,3-Dibromo-1-phenylpentane.
B. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 2 Q. 2,3- Dibromohexanedial.
C. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 3 R. 2- ( 4- isobutylphenyl) propanoic acid
D. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 4 S. 2- Hydroxy-1,2,3- propanetricarboxylic acid.

Match the structures in Column I with their correct IUPAC names given in Column II.

Column I Column II
A. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 1 P. 2,3-Dibromo-1-phenylpentane.
B. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 2 Q. 2,3- Dibromohexanedial.
C. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 3 R. 2- ( 4- isobutylphenyl) propanoic acid
D. COMEDK 2025 Morning Shift Chemistry - IUPAC Nomenclatures Question 3 English 4 S. 2- Hydroxy-1,2,3- propanetricarboxylic acid.

Q.56 Correct
Q.56 In-correct
Q.56 Unattempt

Match the reactions of Glucose given in Column I with the major product formed in the reaction as in Column II.

Column I - Reactions Column II - Major product
A. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{HI}$ (Heat) P. $\mathrm{HOOC}-(\mathrm{CHOH})_4-\mathrm{COOH}$
B. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{Br}_2(\mathrm{aq})$ Q. $\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_4-\mathrm{CH}_3$
C. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+$ Conc. $\mathrm{HNO}_3$ R. $\mathrm{NH}_4 \mathrm{O}-\mathrm{OC}-(\mathrm{CHOH})_4-\mathrm{CH}_2 \mathrm{OH}$
D. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+2\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right] \mathrm{OH}$ S. $\mathrm{HOOC}-(\mathrm{CHOH})_4-\mathrm{CH}_2 \mathrm{OH}$

Match the reactions of Glucose given in Column I with the major product formed in the reaction as in Column II.

Column I - Reactions Column II - Major product
A. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{HI}$ (Heat) P. $\mathrm{HOOC}-(\mathrm{CHOH})_4-\mathrm{COOH}$
B. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{Br}_2(\mathrm{aq})$ Q. $\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_4-\mathrm{CH}_3$
C. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+$ Conc. $\mathrm{HNO}_3$ R. $\mathrm{NH}_4 \mathrm{O}-\mathrm{OC}-(\mathrm{CHOH})_4-\mathrm{CH}_2 \mathrm{OH}$
D. $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+2\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right] \mathrm{OH}$ S. $\mathrm{HOOC}-(\mathrm{CHOH})_4-\mathrm{CH}_2 \mathrm{OH}$

Q.58 Correct
Q.58 In-correct
Q.58 Unattempt

The following results were obtained during study of the reaction $2 \mathrm{NO}(\mathrm{g})+\mathrm{Cl}_2(\mathrm{~g}) \rightarrow 2 \mathrm{NOCl}(\mathrm{g})$. Determine the value of $[\mathrm{X}]$ in $\mathrm{mol} / \mathrm{L}$

Experiment [NO]
mol / L
[Cl$_2$]
mol / L
Initial rate of formation. [NOCl]
mol / L / min
I 0.2 0.2 $6.0 \times 10^{-3}$
II 0.2 0.4 $2.4 \times 10^{-2}$
III 0.4 0.2 $1.2 \times 10^{-2}$
IV X 0.6 $1.35 \times 10^{-1}$

The following results were obtained during study of the reaction $2 \mathrm{NO}(\mathrm{g})+\mathrm{Cl}_2(\mathrm{~g}) \rightarrow 2 \mathrm{NOCl}(\mathrm{g})$. Determine the value of $[\mathrm{X}]$ in $\mathrm{mol} / \mathrm{L}$

Experiment [NO]
mol / L
[Cl$_2$]
mol / L
Initial rate of formation. [NOCl]
mol / L / min
I 0.2 0.2 $6.0 \times 10^{-3}$
II 0.2 0.4 $2.4 \times 10^{-2}$
III 0.4 0.2 $1.2 \times 10^{-2}$
IV X 0.6 $1.35 \times 10^{-1}$

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