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Solutions
Here, we use the BODMAS table given below:

Given:
⇒ 25 * 82 * 12 * 6 * 8 * 91
(1) -, ×, +, ÷, =
⇒ 25 * 82 * 12 * 6 * 8 * 91
After putting the signs:
⇒ 25 - 82 × 12 + 6 ÷ 8 = 91
Apply BODMAS rule:
⇒ 25 - 82 × 12 + 0.75
⇒ 25 - 984 + 0.75
⇒ 25.75 - 984 = (-958.25)
Here, the equation is not satisfied.
(2) ÷, +, -, ×, =
⇒ 25 * 82 * 12 * 6 * 8 * 91
After putting the signs:
⇒ 25 ÷ 82 + 12 - 6 × 8 = 91
Apply BODMAS rule:
⇒ 0.304 + 12 - 6 × 8
⇒ 0.304 + 12 - 48
⇒ 12.304 - 48 = (-35.69)
Here, the equation is not satisfied.
(3) +, -, ÷, ×, =
⇒ 25 * 82 * 12 * 6 * 8 * 91
After putting the signs:
⇒ 25 + 82 - 12 ÷ 6 × 8 = 91
Apply BODMAS rule:
⇒ 25 + 82 - 2 × 8
⇒ 25 + 82 - 16
⇒ 107 - 16 = 91
⇒ '25 + 82 - 12 ÷ 6 × 8 = 91'
Here, the equation is satisfied.
(4) ×, +, ÷, -, =
⇒ 25 * 82 * 12 * 6 * 8 * 91
After putting the signs:
⇒ 25 × 82 + 12 ÷ 6 - 8 = 91
Apply BODMAS rule:
⇒ 25 × 82 + 2 - 8
⇒ 2050 + 2 - 8
⇒ 2052 - 8 = 2044
Here, the equation is not satisfied.
Hence, the correct answer is "Option (3)".