Solutions

Let's check each option,
Given Equation:
167 + 85 – 5 × 4 ÷ 36 = 199
1) ÷ and × →
→ 167 + 85 – 5 ÷ 4 × 36 = 199
→ 167 + 85 – 45 = 199
→ 252 – 45 = 199
→ 207 ≠ 199
→ LHS ≠ RHS
2) ÷ and - →
→ 167 + 85 ÷ 5 × 4 - 36 = 199
→ 167 + 17 × 4 - 36 = 199
→ 167 + 68 - 36 = 199
→ 235 - 36 = 199
→ 199 = 199
→ LHS = RHS → Satisfies the equation.
3) × and + →
→ 167 × 85 – 5 + 4 ÷ 36 = 199
→ 167 × 85 – 5 + 0.11 = 199
→ 14195 – 5 + 0.11 = 199
→ 14195.11 – 5 = 199
→ 14190.11 – 5 ≠ 199
→ LHS ≠ RHS
4) - and × →
→ 167 + 85 × 5 - 4 ÷ 36 = 199
→ 167 + 85 × 5 - 0.11 = 199
→ 592 - 0.11 = 199
→ 591.89 ≠ 199
→ LHS ≠ RHS
Here, we can see that only Option 2 satisfies the equation.
Hence, the correct answer is "÷ and -".