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Solutions
CONCEPT :
Types of figure generally given in the exams.

The clearly seen alternate position of the open dice becomes the opposite pair after folding and the two remaining faces also become opposite to each other.
Here, In every figure:
A is opposite to C.
B is opposite to D.
Thus the remaining, E is opposite to F.
Important Points
The opposite pair of faces will never appear in the adjacent position of a dice.
EXPLANATION:
The alternate position of faces becomes opposite to each other, as shown below:

The opposite pairs are (1, 3), (2, 4) and the remaining ( 5, 6).
The face opposite to the face having the number 5 is 6.
CONCLUSION :
Hence, option 3 is the correct answer.