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d and f-Block Elements Test - 4
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d and f-Block Elements Test - 4
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  • Question 1/8
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    The equivalent weight of MnSO4 is ___ of its molecular weight when it is converted to MnO2.

    Solutions

    Oxidation state of Mn in MnSO4 = +2
    Oxidation state of Mn in MnO2 = +4
    The increase in oxidation state is 2. Therefore, the equivalent weight of MnSO4 is half of its molecular weight when it is converted to MnO2 .

     

  • Question 2/8
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    Given below are some points of comparison between actinoids and lanthanoids. Choose the incorrect statements from among them.

    a. Actinoids show greater number of oxidation states than lanthanoids.
    b. The chemistry of actinoids elements is not so smooth as that of lanthanoids.
    c. Most of the cations of actinoids and lanthanoids are coloured.

    Solutions

    All the given statements are correct.
    a. Actinoids show greater number of oxidation states than lanthanoids. This is because the 5f orbitals extend further from the nucleus than the 4f orbitals.
    b. The chemistry of actinoids elements is not so smooth as that of lanthanoids.
    c. Most of the cations of actinoids and lanthanoids are coloured.

     

  • Question 3/8
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    Which of following is used in the preparation of the optical glass of the camera having a high refractive index?

    Solutions

    Lanthanum oxide is added to the glass of optical instruments to raise the refractive index of glass and to increase the stability.
    Neodymium and praseodymium oxides are used for making coloured glasses for goggles.

     

  • Question 4/8
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    Directions For Questions

    The following question has four choices, out of which ONLY ONE is correct.

    ...view full instructions


    The correct order of ionic radii of Yb3+, La3+, Eu3+ and Lu3+ is:

    Solutions

    In the lanthanide series, there is a regular decrease in the atomic as well as ionic radii with the increase in the atomic number. This is referred to as the lanthanide contraction.

    Although the atomic radii do show some irregularities in the trend, the ionic radii of the trivalent ions (M3+) decrease with the increase in the atomic number, i.e. from La+3 (106 pm) to Lu3+ (86 pm).

     

  • Question 5/8
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    In which of the following pairs of elements, does the element with the higher atomic number have a lower ionization energy as compared to the preceding element?

    Solutions

    The ionization energy values increase across the period due to increase in the effective nuclear charge.
    However, even though Ni has a higher atomic number than cobalt, it has a lower ionization energy.
    This may probably be, because Co with a slightly higher atomic mass has a slightly stronger pull on the valence electrons.

     

  • Question 6/8
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    Directions For Questions

    The following question has four choices, out of which ONLY ONE is correct.

    ...view full instructions


    For Cr, the oxidation states (+ 2), (+ 3) and (+ 4) are well known, but the most stable oxidation state amongst these is

    Solutions

    Cr+3 is the most stable oxidation state of Cr as the trivalent cation of chromium has a stable electronic configuration of half filled t2g orbitals.
    In this state, chromium is neither oxidizing nor reducing.

     

  • Question 7/8
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    The values of the reduction potentials of Cr3+ and Mn3+ are -0.41V and +1.51V, respectively. Choose the option that is inferred from the given factual information?

    Solutions

    Mn2+ has a stable configuration of half filled d- orbitals and Mn3+ is readily reduced to Mn2+.

    Therefore, Mn3+ is a good oxidizing agent.

    The other statements are wrong as Cr+3 is more stable than Cr+2 and as a result Cr+2 is a strong reducing agent.

     

  • Question 8/8
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    H2Ogives blue colour on treatment with acidified solution of potassium dichromate. This is due to the formation of

    Solutions

    K2Cr2O+ H2SO4 + 4H2O2 → 2CrO5 (chromic peroxide) + K2SO4 + 5H2O
    The blue colour due to chromic peroxide fades away gradually due to decomposition of CrO5 to Cr3+ ions and oxygen.

     

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