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Which of the following causes laxative effect when present above 500 ppm in water :
Which is not a pair of reducing sugars-
Given the value of their van der Waals’ constant ‘a’ arrange the following gases in the order of their expected liquification pressure at a temperature T. T is below the critical point of all the
gases.
Gas CH4 Kr N2 Cl2
‘a’(atmL2.mol–2) 2.283 2.439 1.408 6.579
Which of the following d-block element has highest stable oxidation state.
Find D
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Calculate ΔSuniverse for following chemical reaction
C (graphite) + 2H2(g) → CH4(g);
ΔfH° = –74.81 kJ at 298 K.
The standard entropies of C (graphite), H2(g) and CH4(g) are 5.740, 130.684 and 186.264 J/K-mol, respectively.
ΔSReaction = [186.264] – [5.740 + 2 ×130.684)] or ΔSSystem = – 80.844 J/K
ΔSSurrounding = + ΔH/T = 74.81 × 103 / 298 = 251 j/k
ΔSUniverse = – 80.844 + 251 = 170.1 J/K
Some white colourless crystals are heated. A cracking sound is heard and brown fumes are given off and the residue left is yellow-brown in colour. When a glowing splinter is held in the fumes, it is relighted. The fumes consist of :
Pb(NO3)2 PbO + 2 NO2 + 1/2 O2
Vicinal diol compounds breakdown
by HIO4.
Which of the following structure is correctly drawn according to fundamental idea of VSEPR theory-
(A) θ incorrect less than 109º28'
(B) incorrect position of lone pair
(C) correct square planar structure with θ = 90º
(D) θ incorrect because it is square planar with two lone pair at Xe and θ = 90º
The end products of following reaction would be,
3 moles of HCHO give cross aldol condensation with aromatic ketone one mole of HCHO under goes cross Cannizaro reaction with the aldol product.
Correct (-)
Wrong (-)
Skipped (-)