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Joule-Thomson coefficient (∂T/∂P)H for an ideal gas is:
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Ideal gas does not show Joule-Thomson effect.
All the three states H2O, i.e., the triple point for H2O the equilibrium,
Ice ⇌ Water ⇌ Vapour exist at:
The conditions for triple point of H2O.
the particular temperature and pressure at which the solid, liquid, and gaseous phases of a given substance are all at equilibrium with one another.
A gas cannot be liquefied if:
Hint: In the case of Ideal gas, the force of attraction between molecules is zero.
Ideal gas molecules are separated from each other by large space and the actual volume of the gas molecule is negligible with respect to the volume of gas. Due to large intermolecular spaces, there is no force of attraction between the ideal gas molecules and they are completely independent of each other.
The gas among the following can be most steadily liquefied is -
Hint: Gas having a high force of attraction liquify easily
SO2 has a higher value of van der Waals' forces of attraction and thus, is more easily liquefied.
value of 'a" for
SO2 has higher value of "a" hence it has maximum forces of attraction, thus, it will liquify easily.
The correct statement regarding the van der Waal constant of N2 & NH3 is -
Hint- a is measure of intermolecular strength and b depends upon molecular weight
EXPLANATION
Higher the polarity, easier to liquify.
The ease of liquification of a gas depends on their intermolecular force of attraction which in turn is measured in terms of van der Waals’ constant ‘a’.
Hence, higher the value of ‘a’, greater the intermolecular force of attraction, easier the liquification.
In the present case, NH3 has highest ‘a’, can most easily be liquefied.Molecular weight of nitrogen is greater than ammonia ,SO the value of b for nitrogen
Maximum deviation from ideal gas is shown by-
Hint: Easily liquefiable gases exhibit maximum deviation
Easily liquefiable gases like NH3, SO2 etc. exhibit maximum deviation from ideal gas as for them Z<<< 1 .
CH4 also exhibits deviation but it is less as compared to NH3.
Joule-Thomson expansion of an ideal gas is an
Joule-Thomson effect occurs at constant enthalpy.
Choose the correct statement for viscosity (η) variation with T and P for an ideal gas-
In the case of gases, the viscous resistance arises from the transport of molecules from one layer to another, with transfer of momenta, so that the fast moving molecules in one layer are slowed down, while the slow moving molecules in the other are accelerated. This momentum transfer increases with increase in temperature. A simple expression for the viscosity of a gas
The critical temperature and critical pressure of a gas obeying Van dar Waal's equation are 30oC and 73 atm, respectively. Its Van der Waal's constant b (in litres mol−1) is:
The critical volume of a gas is 0.072 lit. mol−1. The radius of the molecule will be, in cm:
The critical volume is three times the Van der Waals constant 'b'.
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