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Chemistry Test 130
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Chemistry Test 130
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  • Question 1/10
    4 / -1

    The uncertainity found from the uncertainity principle (Δx.Δp = h / 4π) is

    Solutions

    Δx.Δp ≧ h / 4π

    So by the equation given in the question, the uncertainity value will be the least.

     

  • Question 2/10
    4 / -1

    The number of orbitals in any shell (n) is equal to

    Solutions

    Maximum number of electrons can be accommodated in a shell of principal quantum number n is 2n2. Since each orbital can accommodate only 2 electrons, maximum number of orbitals =2n2/2= n2

     

  • Question 3/10
    4 / -1

    The maximum number of 4f electrons having spin quantum number (-1/2) is

    Solutions

    Total no. of electrons in F- subshell = 14 (when we include both spin +1/2  & - 1/2)

    But maximum no. of electrons = 7 if only one spin either - 1/2 or +1/2.

     

  • Question 4/10
    4 / -1

    The number of unpaired electrons in Cu+ (Z= 29) is

    Solutions

    Answer : The electronic configuration of Cu is,

    1s22s22p63s23p64s13d10

    The reason for abnormal electronic configuration of Cu is because of the half-filled and fully-filled configuration are the more stable configuration. In this configuration, the d-subshell is fully-filled and s-subshell is half-filled which makes the Cu more stable.

    Now, for getting a positive charge, it has to lose 1 electron which will be removed from the outermost 4s orbital and hence all the remaining electrons will be paired leading to 0 unpaired electrons.

     

  • Question 5/10
    4 / -1

    The electrons present in K-shell of the atom will differ in

    Solutions

    Two electrons in K-shell will differ in spin quantum number.

    They will have same values for the principal quantum number, azimuthal quantum number, and magnetic quantum number.

    For first electron, n = 1,l = 0,m = 0,s = +1 ​/ 2

    For second electron, n = 1,l = 0,m = 0,s = −1 / 2

     

  • Question 6/10
    4 / -1

    Directions For Questions

    Consider the following statements. The d-orbitals have

    I. four lobes and two nodes

    II. four lobes and one node

    III. same sign in the opposite lobes

    IV. opposite sign in the opposite lobes

    ...view full instructions


    Which of the above statements are correct ? 

    Solutions

    Total no of angular nodes = l (azimuthal quantum no), so l=2 in d orbital, therefore number of nodes is 2 and it is a fact that opposite lobes have same signs and adjacent ones have opposite signs. there are 4 lobes in d orbital.

     

  • Question 7/10
    4 / -1

    Which of the following substances has the lowest boiling point?

    Solutions

    Boiling Point is directly proportional to VanderWaals forces of attraction. Down the group, this forces increases. so force of attraction in CHF3 is weaker than CHL3, that's why boiling point of CHF3 is lowest.

     

  • Question 8/10
    4 / -1

    Which of the following is solid with highest melting point ?

    Solutions

    SiO2 is a covalent 'network' solid. So the energy required to break bonds will be higher. Therefore the melting point will be higher.

     

  • Question 9/10
    4 / -1

    Out of the two compounds shown below, the vapour pressure of B at a particular temperature is expected to be

    Solutions

    Due to intramolecular H-bonding  in o-nitrophenol it exists as a monomer while due to intermolecular H-bonding in p-nitrophenol it exists as an associate molecule. As a result, vapour pressure of a o-nitrophenol is higher than that of a p-nitrophenol.

     

     

  • Question 10/10
    4 / -1

    In which of the following molecules, the central atom does not have sp3 hybridisation?

    Solutions

    When the number of hybrid orbitals, H  is 4, the hybridization is sp3 hybridization

    H = 1 / 2[V + M - C + A]

    where, V = number of monovalent atoms

    C = total positive charge

    A = negative charge

    a) For CH4

    H = 1 / 2[4 + 4 - 0 + 0] = 4

    sp3 

    b) For SF4,

    H = 1 / 2 [6 + 4 - 0 + 0] = 5

    sp3d

    c) For BF-4,

    H = 1 / 2 [3 + 4 - 0 + 1] = 4, thus sp3

    d) For NH+4

    H = 1 / 2[5 + 4 - 1 + 0] = 4 thus sp3

    Thus, only in SF4 the central atom does not have sp3 hybridisation.

     

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