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Alcohols Test - 6
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Alcohols Test - 6
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  • Question 1/10
    1 / -0.25

    Which of the following reacts with alcohols to form esters besides carboxylic acids?

    Solutions

    The correct answer is option D
    Acyl chloride
    Esters are derived from carboxylic acids. A carboxylic acid contains the -COOH group, and in an ester the hydrogen in this group is replaced by a hydrocarbon group of some kind. We shall just be
    looking at cases where it is replaced by an alkyl group, but it could equally well be an aryl group (one based on a benzene ring).
    A common ester - ethyl ethanoate
    The most commonly discussed ester is ethyl ethanoate. In this case, the hydrogen in the -COOH group has been replaced by an ethyl group

  • Question 2/10
    1 / -0.25

    What happens when phenol is treated with ammonia in the presence of anhydrous ZnCl2 ?

    Solutions

    The correct answer is Option D.

  • Question 3/10
    1 / -0.25

     When aryl halide is heated with 6-8% NaOH solution ,at 623 K under 300 atm pressure we get:

    Solutions

    The correct answer is Option A.
     
    The aryl halide is heated with 6-8%. NaOH solution at 623K under 300 atm pressure 1) it gives sodium phenoxide 2) sodium phenoxide treated with HCl(acidification) then it gives phenol.

  • Question 4/10
    1 / -0.25

    Which alkene is obtained on dehydration of the following alcohol in the presence of H2 SO4  ?

    Solutions

     

    Carbonium ion formed in 1st  step undergoes rearrangement to give tert. carbonium ion since tert-carbonium ions are more stable than secondary one.

  • Question 5/10
    1 / -0.25

    What is the product formed when excess of ethanol reacts with concentrated sulphuric acid at 383 K and then the temperature of reaction mixture is increased to 443 K?

    Solutions

  • Question 6/10
    1 / -0.25

    Identify the alcohol or phenol from the following which is most soluble in water.

    Solutions

    The correct answer is option A
    Amongst isomeric alcohols, the solubility increases with branching. This is due to the reason that as the branching increases, the surface area of the non-polar hydrocarbon and the solubility increases.

  • Question 7/10
    1 / -0.25

    Which of the following statement is correct?

    Solutions

    The correct answer is Option D.

    Phenols have higher boiling point than toluene due to the presence of intermolecular hydrogen bonding in phenols. The formation of hydrogen bonds increases the intermolecular force of attraction between the phenol molecules and thereby increases its boiling point.

  • Question 8/10
    1 / -0.25

    Isopropyl alcohol on oxidation forms:

    Solutions

    The correct answer is Option A.

    Isopropyl alcohol forms acetone on oxidation. 
     
    The reaction is as follows:

  • Question 9/10
    1 / -0.25

    Which catalyst is used in Fischer-Speier esterification?

    Solutions

    Fischer Esterification is an organic reaction that is employed to convert carboxylic acids in the presence of excess alcohol and a strong acid catalyst to give an ester as the final product. This ester is formed along with water.

    • The esterification of Fischer is one of the most common carboxylic acid reactions. Treatment with alcohol of carboxylic acids in the presence of acid catalyst contributes to the formation of esters along with the removal of a water molecule.
    • Fischer esterification uses sulphuric acid as a catalyst. It protonates the carboxylic acid carbonyl group and not the feature of hydroxyl.

  • Question 10/10
    1 / -0.25

    Fermentation of Glucose to alcohol undergoes in presence of :

    Solutions

    The correct answer is option D
    Zymase is an enzyme complex that catalyzes the fermentation of sugar into ethanol and carbon dioxide. It occurs naturally in yeasts. Zymase activity varies among yeast strains. Zymase is also the brand name of the drug pancrelipase.

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