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Solutions Test - 6
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Solutions Test - 6
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  • Question 1/15
    1 / -0.25

    Which one of the following is not a colligative property?

    Solutions

    Depression in freezing point is a colligative property but freezing point is not a colligative property.

  • Question 2/15
    1 / -0.25

    The molal elevation constant is the elevation in boiling point of

    Solutions

    The correct answer is Option B.
     
    Molal elevation constant is a characteristic constant for a given solvent. It is the elevation of boiling point produced when one mole of solute is dissolved in 1 kg of solvent. The proportionality constant, Kb, is called the molal boiling point elevation constant. It is a constant that is equal to the change in the boiling point for a 1-molal solution of a nonvolatile molecular solute.

  • Question 3/15
    1 / -0.25

    The colligative properties of a solution are

    Solutions

    The correct answer is option A
    The colligative properties of a solution are
    Proportional to the number of solute particles present.
    In chemistry, colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent molecules in a solution, and not on the nature of the chemical species present.

  • Question 4/15
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    The information that is/are needed to determine the molar mass of an unknown solute is/are

    Solutions

    Elevation of boiling point and depression in freezing point are directly related to molality of solution.

  • Question 5/15
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    What is the boiling point of a 3 molal aqueous solution if Kb is 0.512 °C/m?

    Solutions

  • Question 6/15
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    Which of the following is a colligative property?

    Solutions

    Colligative properties- The properties that depend upon the ratio of the number of solute molecules and total molecules not upon the nature of solute molecules named as colligative properties.

    Example- Osmotic pressure, elevation of boiling point, depression in freezing point and relative lowering of vapour pressure.

  • Question 7/15
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    Beckmann thermometers are used to measure

    Solutions

    The correct answer is Option B.
    A Beckmann 's thermometer is a device used to measure elevation in boiling point or depression in freezing point.

  • Question 8/15
    1 / -0.25

    A solution was made by dissolving 2 g of a solute in 100 g of acetone. The solution boiled at 56.95 °C. The boiling point of pure acetone is 55.95 °C, and the Kb =1.71 °C/m. What is the molecular weight of the solute?

    Solutions

    The correct answer is Option B.
     
    ∆Tb =(Kb ×1000 ×W2 ) / M2 ×W1
    ⇒M2 = (Kb ×1000 ×W2 ) / ∆Tb ×W1
    = (1.71 ×1000 ×2) / 1 ×100
    = 34.2g

  • Question 9/15
    1 / -0.25

    The molal elevation constant is the ratio of the elevation in B.P to:

    Solutions

    The correct answer is option A
    Due to solute presence in the solution, the solution 's boiling point is greater than the pure solvent 's boiling point. This is called as elevation in boiling point and it can be represented as:
    ΔTb ​=Kb ​×molality

  • Question 10/15
    1 / -0.25

    Which of the two has lower freezing point, 2m NaCl or 5m NaCl aqueous solution?

    Solutions

    The correct answer is option C  
    ΔTf = Kf  x m Since ΔTf for 5m NaCl will be higher than for 2m, 5m NaCl solution freezes at a lower temperature.

  • Question 11/15
    1 / -0.25

    If the vapour pressure of pure solvent A is 17.5 mm and lowering of vapour pressure of solution formed by adding a non-volatile electrolyte is 0.0175 mm then what is the relative lowering of vapour pressure?

    Solutions

    The correct answer is option C
    Relative lowering of vapour pressure:
    = lowering of vapour pressure of solution/ vapour pressure of pure solvent
    =0.0175/17.5=0.001

  • Question 12/15
    1 / -0.25

    Which of the following unit of concentration is independent of temperature?

    Solutions

    Molality (amount of moles per 1 kg of the solvent, mol/kg) and mole fraction (mol/mol) will remain constant since they are independent of volume of the solution which changes with temperature. Molarity i.e. amount of moles of a substance in 1 liter of a solution will change with volume of the solution so it will change with temperature.

  • Question 13/15
    1 / -0.25

     Relative lowering of vapour pressure is directly proportional to

    Solutions

    Relative lowering of vapour pressure is directly proportional to mole fraction of solute. Hence it is a colligative property.
     

  • Question 14/15
    1 / -0.25

    When common salt is dissolved in water:

    Solutions

    The correct answer is Option B.

    When a non-volatile solute is dissolved in a pure solvent, its vapour pressure is decreased. The difference in the boiling points of the solution and pure solvent is called elevation in boiling point.
     
    The elevation in the boiling point of a solution of nonelectrolyte is proportional to its molality and the equimolal solution of all the substances in the same solvent will show an equal elevation in boiling points. These are known as Raoult 's laws of elevation of the boiling point.
     
    So, the addition of salt will increase the boiling point of the solution.
     

  • Question 15/15
    1 / -0.25

    Camphor is used as solvent to determine the molecular mass of non-volatile solute by Rast method because for camphor

    Solutions

    The correct answer is “molal depression constant is high ”.

    Camphor is used for the determination of molecular masses of solute by Rast method because its molal depression constant is very high 40Kmolality-1 .

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