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The solubility of CaF2 in pure water is 2.3 × 10-4 mol dm-3. Its solubility product will be
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Solubility product = 4S3
= 4(2.3 × 10-4)3
= 4 × 12.167 × 10-12
= 48.67 × 10-12
= 4.867 × 10-11 = 4.9 × 10-11
The solubility of Mg(OH)2 is S moles/litre. The solubility product under the same conditions is
Ksp = [Mg2+] [OH-]2
Ksp = S × (2S)2
Ksp = 4S3
In the reaction 2H2O (g) + 2Cl2 (g) ⇄ 4HCl (g) + O2 (g), the values of Kp and Kc are related as
Therefore, KP > KC for those reactions that proceed with an increase in the number of gaseous moles.
2H2O (g) + 2Cl2 (g) ⇄ 4HCl (g) + O2 (g)
Kp = KcRT
So, Kp > Kc
If the concentration of [Ag+] = 10-5 in a solution, then the concentration of [Cl-] required for the precipitation of AgCl (Ksp = 2 ×10-12) is
Use the expression: Ksp = [Ag+][Cl-]
2 × 10-12 = 10-5 × [Cl-]
[Cl-] = 2 × 10-7
Which of the following compounds is not a protonic acid?
Since B(OH)3 is not able to donate any proton, so it is not a protonic acid.
For a sparingly soluble salt ApBq, the relationship between its solubility product (Ls) and its solubility (S) is
Ap Bq = pA+ + qB-
If S is the solubility,
[A+] = pS, [B-] = qS;
Ksp = [A+]p[B-]q
Ls= (pS)p (qS)q = Sp+q pp qq
What is the maximum concentration of equimolar solution of ferrous sulphate and sodium sulphide, so that when mixed in equal volumes there is no precipitation of iron sulphide? [Ksp for iron sulphide = 6.3 × 10-18]
Let the concentration of FeSO4 and Na2S be x mol L-1.
Then, after mixing equal volumes:
[FeSO4] = [Na2S] = x/2 M
Or [Fe2+] = [S2-] = x/2 M
FeS ⇌ Fe2+ + S2-
Ksp = [Fe2+][S2-]
6.3 × 10-18 = (x/2)(x/2)
On solving, x = 5.02 × 10-9 mol L-1
The solubility product of silver bromide is 5 x 10-13. The quantity of potassium bromide with molar mass 120 g/mol to be added to 1 litre of 0.05 M solution of silver nitrate to start the precipitation of AgBr is
For the equilibrium A ⇋ B, the variation of the rate of the forward (a) and reverse (b) reaction with time is given by
The number of H+ ions in 1 cm3 of a solution having pH = 13 is ___________.
For pH = 13,
[H+] = 10-13 M
Number of moles H+ ions in 1000 cm3(1 L) solution = 10-13
Number of moles of H+ ions in 1 cm3 solution
Number of moles of H+ ions in 1 cm3 solution = Number of moles × 6.023 × 1023
Number of moles of H+ ions in 1 cm3 solution = 10-16 × 6.023 1023 = 6.023 × 107
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