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Calculate the useful work of the reaction Ag(s) + 1/2Cl2 (g) → AgCl(s) Given E °cl2/cl- = + 1.36 V, E °AgCl/Ag,Cl- = 0.22 V
If Pcl2 = 1 atm and T = 298 K
Verify mobile number to view the solution
(1) AgCl (s) + e →Ag(s) + Cl- E0 = 22 V
(2) 1/2 Cl2 + e →Cl- E0 = 1.36V
we get
Ag(s) + 1/2Cl2 (g) →AgCl(s) E0cell = 1.14V
Which of these ions Cu+ , Co3+ , Fe2+ is stable in aqueous medium.
Given :
E ° Cu2+ /Cu+ = 0.15 volt ; E ° Cu+ /Cu = 0.53 V ; E ° Co3+ /Co2+ = 1.82 V ;
E ° Fe3+ /Fe2+ = 0.77 V ; E ° Fe2+ Fe = - 0.44 V ; E ° O2 ,H+ /H2 O = 1.23 V
if reduction potential of metal ion is greater then O2 /H2 O couple, the ion is stable in water. So Co3+ is stable in water
Select the correct statement if -
E ° Mg2+ /Mg = - 2.4V, E ° Sn4+ /Sn2+ = 0.1 V, E ° MnO4- ,H+ /Mn2+ = 1.5 V, E ° I2 /I- = 0.5 V Here,
[Hint: Reverse of (B) &(C) is spontaneous; weakest Oxidizing Agent here is Mg2+ ]
What is the value of pKb (CH3 COOH- ) if λm∞ = 390 &λm = 7.8 for 0.04 of a CH3COOH at 25 °C
The temperature coefficient of a standard Cd-cell is –5.0X10–5 Vk–1 whose emf at 25 °C is 1.018 V. During the cell operation, the temperature will -
A cell Ag | Ag+ || Cu++ | Cu initially contains 2M Ag+ and 2M Cu++ ions. The charger in cell potential after the passage of 10 amp current for 4825 sec is:
For the cell (at 298 K)
Ag(s) | AgCl(s) | Cl- (aq) || AgNO3 (aq) | Ag(s)
Which of the following is correct –
Conductivity is high due to [H+ ]
During an electrolysis of conc. H2 SO4 , perdissulphuric acid (H2 S2 O8 ) and O2 from in equimolar amount. The amount of H2 that will form simultaneously will be (2H2 SO4 →H2 S2 O8 + 2H+ + 2e- )
Statement-1: In electrochemical cell, we cannot use KCI in the salt bridge if anodic or cathodic compartment consists of Ag+ of Pb2+ ion.
Statement-2: Salt bridge is employed to maintain the electrical neutrality and to minimize the liquid-liquid junction potential.
Both (S –1) &(S –2) are true and (S –2) is not the correct explanation of (S –1)
Statement-1: Zinc protect the iron better than tin even after it cracks.
Statement-2: E°OPzn < E°OPfe But E°OPSn > E°OPfe
The correct answer C EZn+2∣Zn < EFe+2∣Fe<E+2Sn∣Sn SPR ↓ Reactivity ↑
Correct (-)
Wrong (-)
Skipped (-)