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Chemistry Test 257
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Chemistry Test 257
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  • Question 1/10
    4 / -1

    Which of the following statements about H3BO3 is not correct ?

    Solutions

    1. It is not a tribasic acid.

    Option (a) is incorrect for H3BO3

    2. Aqueous solution, instead of donating the −OH group it breaks the H−OH bond of water and accepts the −OH group from it leaving in the solution hence it is mono basic acid.

     

  • Question 2/10
    4 / -1

    Solutions

    On doubling the [OCl] keeping the [I] and [OH] constant, the rate of formation of [OI] is doubled, hence the order of reaction with respect to [OCl] is one.

    On doubling the [I] keeping the [OCl] and [OH] constant, the rate of formation of [OI] is doubled, hence the order of reaction with respect to I−is one.

    On changing the [OH] to a half-value, the rate of formation of [OI] is doubled. Hence, the order of reaction with respect to [OH] is −1.

    Hence the rate law is r = k[OCl] [I] [OH]−1 = k[OCl] [I]/[OH]

     

  • Question 3/10
    4 / -1

    The relative basic strength of the compounds is correctly shown in the option.

    Solutions

    In NH3, the lone pair is completely available for donation, hence is most basic whereas NH− NH2 and NH− OH can be considered as derivatives of NH3. Here, H is replaced by −NH2 forming NH− NH2 and −OH forming NH− OH being highly electron withdrawing due to −O will decrease the election density most on −N.

    ∴ Least basic elect;on withdrawing −I-effect of

    −NH2 is less as compared to - OH.

    Hence correct order of basic strength is

    NH> NH− NH> NH− OH

     

  • Question 4/10
    4 / -1

    Dettol is a mixture of

    Solutions

    Dettol is an antiseptic solution composed of two main active ingredients: chloroxylenol and terpeneol. These ingredients are dissolved in a suitable solvent, such as ethanol or isopropyl alcohol.

    • Chloroxylenol is effective against bacteria.
    • Terpeneol contributes deodorant properties.
    • The solvent aids in dissolving these components to create the liquid solution used for antiseptic purposes.

     

  • Question 5/10
    4 / -1

    In KO2, the nature of oxygen species and the oxidation state of oxygen atom are (respectively)

    Solutions

    In KO2, the nature of oxygen species and the oxidation state of oxygen atom are, superoxide and −1/2 respectively.

    Superoxide ion is O-2.

    Let X be an oxidation state of oxygen. The oxidation state of K is +1.

    + 1 + 2(X) = 0

    2X = - 1

    X = -1/2

     

  • Question 6/10
    4 / -1

    Consider separate solutions of 0.500 M C2H5OH (aq), 0.100 M Mg3(PO4)(aq), 0.250 M KBr (aq) and 0.125 M Na3PO(aq) at 25oC. Which statement is true about these solutions, assuming all salts to be strong electrolytes?

    Solutions

     

  • Question 7/10
    4 / -1

    The concentrations of fluoride, lead, nitrate and iron in a water sample from an underground lake were found to be 1000 ppb, 40 ppb, 100 ppm and 0.2 ppm, respectively. This water is unsuitable for drinking due to high concentration of

    Solutions

    Fluoride - 1000 ppb = 1 ppm (which is within the permitted levels, viz. < 10 ppm)

    Lead - 40 ppb (which is within the permitted levels, viz. < 50 ppb)

    Iron - 0.2 ppm( is the maximum permmiscible limit)

    Nitrate - 100 ppm is not suitable for drinking.

    [NO3-] > 50 ppm, in drinking water can cause disease such as methemoglobinemia ('blue baby' syndrome).

  • Question 8/10
    4 / -1

    The synthesis of alkyl fluorides is best accomplished by

    Solutions

     

  • Question 9/10
    4 / -1

    The polymer obtained from the following reactions is:

    Solutions

     

  • Question 10/10
    4 / -1

    When 2-butyne is treated with H2/Lindlar's catalyst, compound X is produced as the major product, and when treated with Na/liq. NH3, it produces y as the major product. Which of the following statements is correct?

    Solutions

    Dipole moment of X is more than Y.

    Boiling point of X is more than Y.

     

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