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Chemistry Test 274
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Chemistry Test 274
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  • Question 1/10
    4 / -1

    Which of the following correctly ranks the cycloalkanes in order of increasing ring strain per methylene group?

    Solutions

    The correct answer is Option B.

    The C-C-C bond angles in cyclopropane (60o) and cyclobutane (90o) are much different than the ideal bond angle of 109.5o.This bond angle causes cyclopropane and cyclobutane to have a high ring strain. However, molecules, such as cyclohexane and cyclopentane, would have a much lower ring strain because the bond angle between the carbons is much closer to 109.5o.

     

  • Question 2/10
    4 / -1

    Which of the following cycloalkanes exhibits the greatest molar heat of combustion per —CH2 — group?

    Solutions

    The correct answer is option D

    Cyclopropane is a cycloalkane molecule with the molecular formula C3H6, consisting of three carbon atoms linked to each other to form a ring, with each carbon atom bearing two hydrogen atoms resulting in D3H molecular symmetry. The small size of the ring creates substantial ring strain in the structure.

     

  • Question 3/10
    4 / -1

    The correct lUPAC name of the compound

    Solutions

    Priority of functional groups is

    - COOH > - CHO >>C = O.

    Hence, the lUPAC name is 4-formyl-2-oxocyclohexane carboxylicacid.

     

  • Question 4/10
    4 / -1

    How many σ and π bonds are present in HC≡C−CH=CH−CH3?

    Solutions

     

  • Question 5/10
    4 / -1

    Arrange in increasing order of basicity. HC≡C−, CH3​CH=CH−, CH3​CH2​−

    Solutions

     

  • Question 6/10
    4 / -1

    What are the hybridization and shapes of the following molecules?

    (i) CH3F

    (ii) HC ≡ N

    Solutions

    CH3F - sp3 hybridised carbon, tetrahedral shape

    (ii) HC = N - sp hybridised carbon, linear shape.

     

  • Question 7/10
    4 / -1

    Q. Consider the following compounds.

    The correct statement regarding properties of above mentioned compounds is/are

    Solutions
    • Both have all their C—C bonds of equal length due to conjugation.
    • I does not decolorises brown colour of bromine water solution but II does as The π bonds in Cyclooctatetraene (Compound II) react as usual for olefins, rather than as aromatic ring systems.
    • I is planar but II is not as it adopts a tub conformation.
    • Cyclooctatetraene shows various other addition reactions including Sulfonation.

    Hence, Option A, B and C are correct.

     

  • Question 8/10
    4 / -1

    What is true about the 1,3,5,7-cyclooctatetraene?

    Solutions

    1-3-5-7-cyclooctatetraene it has 8 pi electrons, and like stated above, fits the criteria of 4n, to be antiaromatic. to avoid this state of anti-aromaticity (less stable then expected), it becomes non-planar, so it can be more stable then it would be in the antiaromatic state. cyclooctatetraene can do this because it can fold, however other 6 carbon compounds that have 4n electrons and are planar can not and result in an antiaromatic compound.

    Potassium cyclooctatetraene is formed by the reaction of cyclooctatetraene with potassium metal:

    2 K + C8H8 → K2C8H8

    The reaction entails 2-electron reduction of the polyene and is accompanied by a color change from colorless to brown.

     

  • Question 9/10
    4 / -1

    The compound shown below evolve hydrogen gas when refluxed with potassium metal, why?

    Solutions

    Metals like Potassium tend to loose their own electrons and the excess electrons will complete the aromaticity of the system.Thus, Deprotonation of the above compound converts it into an aromatic anion witn 6 pi electrons.

     

  • Question 10/10
    4 / -1

    Which of the following behaves both as a nucleophile and as an electrophile?

    Solutions

    R − Cδ = Nδ: has electrophilic C-atom and nucleophilic N-atom.

     

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