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Thevenin voltage is the open-circuit voltage at the load.

Since the load is open-circuited, Vx = Vth
Applying KCL at node Vx, we get:
\(\Rightarrow \frac{{{V}_{x}}-2{{V}_{x}}}{3}+\frac{{{V}_{x}}}{6}+1=0\)
⇒ -2Vx + Vx = -6
Vx = 6 V
∴ Vth = 6V
Now, to evaluate the Thevenin’s Resistance, there are two methods that can be used:
Method 1 (Using a Current source at the load):
Since we have a dependent source present in the circuit, we put a test current source I0 as shown:

Applying KCL at node Vx we get
\(\Rightarrow \frac{{{V}_{x}}-2{{V}_{x}}}{3}+\frac{{{V}_{x}}}{6}-{{I}_{0}}=0\)
\(\Rightarrow \frac{-{{V}_{x}}}{6}={{I}_{0}}\)
Vx = - 6I0 ...1)
Applying KVL from Vx node to V0, we get:
Vx + 3I0 = V0
Using equation (1),
-6I0 + 3I0 = V0,
\(\frac{{{V}_{0}}}{{{I}_{0}}}={{R}_{th}}=-3\text{ }\!\!\Omega\!\!\text{ }\)
Method II (Short cut):
Since the Thevenin and Norton equivalent circuits are related by Superposition Theorem, we can write:
\({{R}_{TH}}=\frac{Open~circuit~voltage}{Short~circuit~current}\)
\({{R}_{th}}=\frac{{{V}_{th}}}{{{I}_{SC}}}\)
To obtain the Thevenin Resistance, we first find the short circuit current through the load as shown:

Applying KCL at node Vx, we get
\(\Rightarrow \frac{{{V}_{x}}-2{{V}_{x}}}{3}+\frac{{{V}_{x}}}{6}+1+\frac{{{V}_{x}}}{3}=0\)
\(\Rightarrow \frac{{{V}_{x}}}{6}=-1\)
Vx = -6V
\(\therefore ~{{I}_{SC}}=\frac{{{V}_{x}}}{3}=\frac{-6}{3}=-2A\)
\(\therefore {{R}_{th}}=\frac{{{V}_{th}}}{{{I}_{SC}}}=-3\text{ }\!\!\Omega\!\!\text{ }\)